Electronic spectra and DFT calculations of hexanuclear chalcocyanide rhenium clusters Full article
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Journal of Physical Chemistry A
ISSN: 1089-5639 , E-ISSN: 1520-5215 |
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| Output data | Year: 2004, Volume: 108, Number: 47, Pages: 10565-10567 Pages count : 3 DOI: 10.1021/jp046753f | ||
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Abstract:
The reaction of one-electron oxidation [Re6Se8(CN)6]4- − [e]- → [Re6Se8(CN)6]3- is studied in liquid solution of the hexanuclear cluster compound (NBu4)4[Re6Se8(CN)6]. The electronic absorption spectra and DFT calculations indicate that the reaction and the final compound (NBu4)3[Re6Se8(CN)6] production may be accomplished through the excited state of paramagnetic hexanuclear chalcocyanide rhenium clusters.
Cite:
Kozlova S.G.
, Gabuda S.P.
, Brylev K.A.
, Mironov Y.V.
, Fedorov V.E.
Electronic spectra and DFT calculations of hexanuclear chalcocyanide rhenium clusters
Journal of Physical Chemistry A. 2004. V.108. N47. P.10565-10567. DOI: 10.1021/jp046753f WOS Scopus РИНЦ OpenAlex
Electronic spectra and DFT calculations of hexanuclear chalcocyanide rhenium clusters
Journal of Physical Chemistry A. 2004. V.108. N47. P.10565-10567. DOI: 10.1021/jp046753f WOS Scopus РИНЦ OpenAlex
Dates:
| Submitted: | Jul 22, 2004 |
| Published online: | Sep 2, 2004 |
Identifiers:
| Web of science: | WOS:000225227300024 |
| Scopus: | 2-s2.0-10044267831 |
| Elibrary: | 13465071 |
| OpenAlex: | W2952422069 |