Synthesis and structures of new octahedral water-soluble heterometal rhenium–molybdenum clusters

Synthesis and structures of new octahedral water-soluble heterometal rhenium–molybdenum clusters Full article

Journal

Polyhedron
ISSN: 1873-3719 , E-ISSN: 0277-5387

Output data

Year: 2004, Volume: 23, Number: 4, Pages: 599-603 Pages count : 5 DOI: 10.1016/j.poly.2003.10.017

Authors

Naumov Nikolai G ^1,2 , Brylev Konstantin A ² , Mironov Yuri V ² , Virovets Alexander V ² , Fenske Dieter ³ , Fedorov Vladimir E ^1,2

Affiliations

1	Novosibirsk State University
2	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
3	Institut für Anorganische Chemie, Universität Karlsruhe

The interaction of polymeric Re3MoS4Te4 with molten KCN at 850 °C results in rearrangement of the tetrahedral {Re3MoS4} cluster core to an octahedral one, {Re6−xMoxS8}, and formation of two new molecular octahedral heterometal rhenium–molybdenum thiocyanide cluster complexes, [Re5MoS8(CN)6]5− and [Re4Mo2S8(CN)6]5−, co-existing in the crystals Cs5[Re4.5Mo1.5(μ3-S)8(CN)6]·2H2O. The EDAX analyses and magnetic measurements data confirm the presence of a mixture of cluster anions with x=1 and 2.

Naumov N.G. , Brylev K.A. , Mironov Y.V. , Virovets A.V. , Fenske D. , Fedorov V.E.
Synthesis and structures of new octahedral water-soluble heterometal rhenium–molybdenum clusters
Polyhedron. 2004. V.23. N4. P.599-603. DOI: 10.1016/j.poly.2003.10.017 WOS Scopus РИНЦ OpenAlex

Submitted:	Jul 9, 2003
Published online:	Jan 28, 2004

Web of science:	WOS:000189216400012
Scopus:	2-s2.0-1042266348
Elibrary:	13457146
OpenAlex:	W2006178578

DB	Citing
Web of science	14
Scopus	20
Elibrary	18
OpenAlex	17