Реферат: The reactions of magnesium nitrate with trans-1,4-cyclohexanedicarboxylic acid (H2Сhdc) in N,N-dimethylformamide (DMF) and N-methylpyrrolidone (NMP) as solvents afford new coordination polymers [Mg3(DMF)4(Chdc)3] (I), [Mg3(DMF)2(NMP)2(Сhdc)3] (II), and [Mg3(NMP)4(Сhdc)3] (III). Coordination polymer [Ca3(NMP)4(Chdc)3] (IV) is synthesized from calcium acetate and H2Chdc in NMP. The reaction of cadmium nitrate with H2Сhdc and urotropine (Ur) in DMF gives coordination polymer [Cd(Ur)(DMF)(Chdc)] (V). The structures of the synthesized compounds are determined by single-crystal X-ray diffraction (XRD) (CIF files CCDC nos. 2120662 (I), 2120666 (II), 2120664 (III), 2120663 (IV), and 2120665 (V)). The coordination polymers of alkaline-earth metals (I–IV) are based on trinuclear carboxylate blocks {M3(OOC)6} linked by the dicarboxylate linkers into trigonal layers. The cadmium compound (V) is built of the mononuclear fragments {Cd(NUr)2(DMF)(OOC)2} linked by bridging trans-1,4-cyclohexanedicarboxylates and urotropine molecules into polymer layers. Compounds I–III are characterized by IR spectroscopy, elemental analysis, and thermogravimetric analysis.

Библиографическая ссылка: Demakov P.A. , Fedin V.P.
Layered trans-1,4-Cyclohexanedicarboxylates of Divalent Metals: Synthesis, Crystal Structures, and Thermal Properties
Russian Journal of Coordination Chemistry. 2022. V.48. N5. P.270-277. DOI: 10.1134/s1070328422050049 WOS Scopus РИНЦ OpenAlex

Оригинальная: Демаков П.А. , Федин В.П.
СЛОИСТЫЕ ТРАНС-1,4-ЦИКЛОГЕКСАНДИКАРБОКСИЛАТЫ ДВУХВАЛЕНТНЫХ МЕТАЛЛОВ: СИНТЕЗ, КРИСТАЛЛИЧЕСКАЯ СТРУКТУРА И ТЕРМИЧЕСКИЕ СВОЙСТВА
Координационная химия. 2022. Т.48. №5. С.269-276. РИНЦ

Даты:

Поступила в редакцию:	12 нояб. 2021 г.
Опубликована в печати:	2 июн. 2022 г.

Идентификаторы БД:

Web of science:	WOS:000805185600002
Scopus:	2-s2.0-85131127257
РИНЦ:	48719345
OpenAlex:	W4281617066

Цитирование в БД:

БД	Цитирований
Web of science	2
Scopus	2
РИНЦ	2
OpenAlex	2

Альметрики: