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Zn(II) coordination polymer with π-stacked 4,4′-bipyridine dimers: Synthesis, structure and luminescent properties Научная публикация

Журнал Polyhedron
ISSN: 1873-3719 , E-ISSN: 0277-5387
Вых. Данные Год: 2022, Том: 219, Номер статьи : 115793, Страниц : 5 DOI: 10.1016/j.poly.2022.115793
Авторы Demakov Pavel A. 1 , Ryadun Alexey A. 1 , Fedin Vladimir P. 1
Организации
1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, Russia

Реферат: A new metal–organic coordination polymer [Zn2(bpy)2(NO3)2(chdc)] (1; bpy = 4,4′-bipyridine, chdc2– = trans-1,4-cyclohexanedicarboxylate) was synthesized and characterized. This compound is based on the nitrate-capped binuclear {Zn2(Nbpy)4(NO3)2(OOCR)2} fragments interconnected by dicarboxylate moieties and π-stacked bpy dimers with ca. 3.53 Å interplanar distance to form a two-dimensional (2D) sql network. Thermal and luminescent properties of 1 were investigated. Under excitation from 320 nm to 480 nm, the named compound demonstrates wide-banded yellow emission with the red shift of the maximum from 562 nm to 596 nm, and quantum yields up to 6.7%.
Библиографическая ссылка: Demakov P.A. , Ryadun A.A. , Fedin V.P.
Zn(II) coordination polymer with π-stacked 4,4′-bipyridine dimers: Synthesis, structure and luminescent properties
Polyhedron. 2022. V.219. 115793 :1-5. DOI: 10.1016/j.poly.2022.115793 WOS Scopus РИНЦ OpenAlex
Даты:
Поступила в редакцию: 14 янв. 2022 г.
Опубликована в печати: 1 июн. 2022 г.
Идентификаторы БД:
Web of science: WOS:000793131400006
Scopus: 2-s2.0-85127147648
РИНЦ: 48421343
OpenAlex: W4220949027
Цитирование в БД:
БД Цитирований
Web of science 10
Scopus 9
РИНЦ 10
OpenAlex 9
Альметрики: