METAL-ORGANIC COORDINATION POLYMERS OF LANTHANIDES(III) WITH THIENOTHIOPHENDICARBOXYLATE LIGANDS

METAL-ORGANIC COORDINATION POLYMERS OF LANTHANIDES(III) WITH THIENOTHIOPHENDICARBOXYLATE LIGANDS Full article

Journal

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Output data

Year: 2021, Volume: 62, Number: 10, Pages: 1599-1606 Pages count : 8 DOI: 10.1134/s0022476621100152

Authors

Yudina Yu.A. ^1,2 , Samsonova A.M. ^1,2 , Bolotov V.A. ¹ , Demakov P.A. ¹ , Samsonenko D.G. ¹ , Fedin V.P. ¹ , Dybtsev D.N. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia

Three novel metal-organic coordination polymers based on sulfur-containing thieno[3,2-b]thiophene-2,5-dicarboxylic (trans-H2ttdc) and thieno[2,3-b]thiophene-2,5-dicarboxylic (cis-H2ttdc) acids are obtained: [Ce2(DMF)4(trans-ttdc)3]·2DMF (1), [Dy2(DMF)4(trans-ttdc)3]·4DMF (2), and [Tb2(DMF)4(cis-ttdc)3]·2.5DMF (3). Structures of the products are determined by single crystal X-ray diffraction. The compositions and nature of compounds 2 and 3 are confirmed by IR spectroscopy, elemental and thermogravimetric analyses. All three compounds are based on binuclear {Ln2(DMF)4(RCOO)6} units organized into 3D frameworks with primitive cubic topology pcu by linear organic linkers. The specific void volume in the structures of 1-3 ranges from 29% to 37%.

Yudina Y.A. , Samsonova A.M. , Bolotov V.A. , Demakov P.A. , Samsonenko D.G. , Fedin V.P. , Dybtsev D.N.
METAL-ORGANIC COORDINATION POLYMERS OF LANTHANIDES(III) WITH THIENOTHIOPHENDICARBOXYLATE LIGANDS
Journal of Structural Chemistry. 2021. V.62. N10. P.1599-1606. DOI: 10.1134/s0022476621100152 WOS Scopus РИНЦ OpenAlex

Юдина Ю.А. , Самсонова А.М. , Болотов В.А. , Демаков П.А. , Самсоненко Д.Г. , Федин В.П. , Дыбцев Д.Н.
Металл-органические координационные полимеры лантаноидов(III) с тиенотиофендикарбоксилатными лигандами
Журнал структурной химии. 2021. Т.62. №10. С.1702-1709. DOI: 10.26902/jsc_id85172 РИНЦ OpenAlex

Submitted:	Jul 14, 2021
Published print:	Nov 16, 2021

Web of science:	WOS:000719338400015
Scopus:	2-s2.0-85119130156
Elibrary:	47528788
OpenAlex:	W3213267902

DB	Citing
Web of science	6
Scopus	6
Elibrary	6
OpenAlex	6