CRYSTAL STRUCTURE OF ZINC COORDINATION POLYMERS BASED ON 1,4-DIAZABICYCLO[2.2.2]OCTANE N,N′-DIOXIDE: EFFECT OF HYDROPHOBICITY OF CARBOXYLATE LIGANDS Full article
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Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766 |
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| Output data | Year: 2021, Volume: 62, Number: 3, Pages: 403-411 Pages count : 9 DOI: 10.1134/s0022476621030069 | ||||
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Abstract:
Four novel coordination polymers based on 1,4-diazabicyclo[2.2.2]octane N,N′-dioxide (odabco) with the following formulas [Zn(H2O)2(HCOO)2]·odabco (1), [Zn2(OH)(odabco)2(HCOO)2](NO3) (2), [Zn(odabco) (OAc)2] (3, OAc– = acetate) and [Zn2(odabco)3(OAc)2](NO3)2 (4) are prepared in solvothermal conditions. The structure of these compounds is determined by single crystal X-ray diffraction. The coordination polymer 1 is formate containing odabco guest molecules. The coordination polymers 2-4 contain odabco as a bridging ligand with additional terminally coordinated carboxylate anions. The system of hydrogen bonds in the layered formates 1 and 2 leads to the formation of 3D supramolecular frameworks. The acetates 3 and 4 containing no strong hydrogen bonds are one-dimensional and layered coordination polymers, respectively. It is established that the nature of the carboxylate anion has a decisive effect on the structure of resulting products.
Cite:
Demakov P.A.
, Yudina Y.A.
, Samsonenko D.G.
, Dybtsev D.N.
, Fedin V.P.
CRYSTAL STRUCTURE OF ZINC COORDINATION POLYMERS BASED ON 1,4-DIAZABICYCLO[2.2.2]OCTANE N,N′-DIOXIDE: EFFECT OF HYDROPHOBICITY OF CARBOXYLATE LIGANDS
Journal of Structural Chemistry. 2021. V.62. N3. P.403-411. DOI: 10.1134/s0022476621030069 WOS Scopus РИНЦ OpenAlex
CRYSTAL STRUCTURE OF ZINC COORDINATION POLYMERS BASED ON 1,4-DIAZABICYCLO[2.2.2]OCTANE N,N′-DIOXIDE: EFFECT OF HYDROPHOBICITY OF CARBOXYLATE LIGANDS
Journal of Structural Chemistry. 2021. V.62. N3. P.403-411. DOI: 10.1134/s0022476621030069 WOS Scopus РИНЦ OpenAlex
Original:
Демаков П.А.
, Юдина Ю.А.
, Самсоненко Д.Г.
, Дыбцев Д.Н.
, Федин В.П.
Кристаллическая структура координационных полимеров цинка на основе N,N'-диоксида 1,4-диазабицикло[2.2.2]октана: влияние гидрофобности карбоксилатных лигандов
Журнал структурной химии. 2021. Т.62. №3. С.429-438. DOI: 10.26902/jsc_id69893 РИНЦ OpenAlex
Кристаллическая структура координационных полимеров цинка на основе N,N'-диоксида 1,4-диазабицикло[2.2.2]октана: влияние гидрофобности карбоксилатных лигандов
Журнал структурной химии. 2021. Т.62. №3. С.429-438. DOI: 10.26902/jsc_id69893 РИНЦ OpenAlex
Dates:
| Submitted: | Oct 16, 2020 |
| Published print: | Apr 16, 2021 |
Identifiers:
| Web of science: | WOS:000640793400006 |
| Scopus: | 2-s2.0-85104526182 |
| Elibrary: | 46023555 |
| OpenAlex: | W3153483470 |