Abstract: Four novel coordination polymers based on 1,4-diazabicyclo[2.2.2]octane N,N′-dioxide (odabco) with the following formulas [Zn(H2O)2(HCOO)2]·odabco (1), [Zn2(OH)(odabco)2(HCOO)2](NO3) (2), [Zn(odabco) (OAc)2] (3, OAc– = acetate) and [Zn2(odabco)3(OAc)2](NO3)2 (4) are prepared in solvothermal conditions. The structure of these compounds is determined by single crystal X-ray diffraction. The coordination polymer 1 is formate containing odabco guest molecules. The coordination polymers 2-4 contain odabco as a bridging ligand with additional terminally coordinated carboxylate anions. The system of hydrogen bonds in the layered formates 1 and 2 leads to the formation of 3D supramolecular frameworks. The acetates 3 and 4 containing no strong hydrogen bonds are one-dimensional and layered coordination polymers, respectively. It is established that the nature of the carboxylate anion has a decisive effect on the structure of resulting products.

Cite: Demakov P.A. , Yudina Y.A. , Samsonenko D.G. , Dybtsev D.N. , Fedin V.P.
CRYSTAL STRUCTURE OF ZINC COORDINATION POLYMERS BASED ON 1,4-DIAZABICYCLO[2.2.2]OCTANE N,N′-DIOXIDE: EFFECT OF HYDROPHOBICITY OF CARBOXYLATE LIGANDS
Journal of Structural Chemistry. 2021. V.62. N3. P.403-411. DOI: 10.1134/s0022476621030069 WOS Scopus РИНЦ OpenAlex

Original: Демаков П.А. , Юдина Ю.А. , Самсоненко Д.Г. , Дыбцев Д.Н. , Федин В.П.
Кристаллическая структура координационных полимеров цинка на основе N,N'-диоксида 1,4-диазабицикло[2.2.2]октана: влияние гидрофобности карбоксилатных лигандов
Журнал структурной химии. 2021. Т.62. №3. С.429-438. DOI: 10.26902/jsc_id69893 РИНЦ OpenAlex

Dates:

Submitted:	Oct 16, 2020
Published print:	Apr 16, 2021

Identifiers:

Web of science:	WOS:000640793400006
Scopus:	2-s2.0-85104526182
Elibrary:	46023555
OpenAlex:	W3153483470

Citing:

DB	Citing
Web of science	8
Scopus	8
Elibrary	9
OpenAlex	8

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