Реферат: By a reaction of lanthanide nitrates with trans-1,4-cyclohexane dicarboxylic acid H2chdc in an aqueous medium new coordination polymers with the composition [Ln2(H2O)4(chdc)3] (Ln = Ce (1), Sm (2), Eu (3), Gd (4)) are obtained. Crystallization conditions are optimized with the use of a hexamine-based pH buffer. Compound 1 is additionally characterized by powder X-ray diffraction, elemental and thermogravimetric analyses, and IR spectroscopy. The structure of the obtained compounds is determined by single crystal X-ray diffraction. In a series of isostructural three-dimensional frameworks [Ln2(H2O)4(chdc)3] (Ln = La—Eu, except Pm) a regular change in the structural features is analyzed. The [Gd2(H2O)4(chdc)3] compound has a similar composition but the topology of the three-dimensional network differs from that of the previous ones due to a decrease in the coordination number of metal centers. Heavier lanthanides, starting from Tb3+, and also yttrium(III) do not form compounds with the mentioned composition under similar reaction conditions.

Библиографическая ссылка: Demakov P.A. , Sapchenko S.A. , Samsonenko D.G. , Dybtsev D.N. , Fedin V.P.
Gadolinium Break in a Series of Three-Dimensional trans-1,4-Cyclohexane Dicarboxylates of Rare Earth Elements
Journal of Structural Chemistry. 2019. V.60. N5. P.815-822. DOI: 10.1134/s0022476619050159 WOS Scopus РИНЦ OpenAlex

Даты:

Поступила в редакцию:	16 нояб. 2018 г.
Опубликована в печати:	13 июн. 2019 г.

Идентификаторы БД:

Web of science:	WOS:000471609700015
Scopus:	2-s2.0-85067351270
РИНЦ:	41643553
OpenAlex:	W2949544244

Цитирование в БД:

БД	Цитирований
Web of science	14
Scopus	14
РИНЦ	14
OpenAlex	16

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