A Cryptand Metal-Organic Framework as a Platform for the Selective Uptake and Detection of Group I Metal Cations

A Cryptand Metal-Organic Framework as a Platform for the Selective Uptake and Detection of Group I Metal Cations Full article

Journal

Chemistry: A European Journal
ISSN: 0947-6539 , E-ISSN: 1521-3765

Output data

Year: 2017, Volume: 23, Number: 10, Pages: 2286-2289 Pages count : 4 DOI: 10.1002/chem.201605895

Authors

Sapchenko Sergey A. ^1,2 , Demakov Pavel A. ^1,2 , Samsonenko Denis G. ^1,2 , Dybtsev Danil N. ^1,2 , Schröder Martin ^1,3 , Fedin Vladimir P. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Ave., Novosibirsk, 630090 Russian Federation
2	Department of Natural Sciences, Novosibirsk State University, 2 Pirogova Str., Novosibirsk, 630090 Russian Federation
3	School of Chemistry, University of Manchester, Manchester, M13 9PL UK

The metal–organic framework (MOF) complex (H3O)2[Zn4(ur)(Hfdc)2(fdc)4] (1, ur=urotropine, H2fdc=furan-2,5-dicarboxylic acid) incorporates cryptand-like cavities, which can be used to separate and detect Rb+ and Cs+ optically. This is the first example of the effective employment of a MOF material for optical detection of these cations.

Sapchenko S.A. , Demakov P.A. , Samsonenko D.G. , Dybtsev D.N. , Schröder M. , Fedin V.P.
A Cryptand Metal-Organic Framework as a Platform for the Selective Uptake and Detection of Group I Metal Cations
Chemistry: A European Journal. 2017. V.23. N10. P.2286-2289. DOI: 10.1002/chem.201605895 WOS Scopus РИНЦ OpenAlex

Submitted:	Dec 19, 2016
Published print:	Feb 16, 2017

Web of science:	WOS:000395583200009
Scopus:	2-s2.0-85010223518
Elibrary:	29473560
OpenAlex:	W2573307531

DB	Citing
Web of science	18
Scopus	20
Elibrary	18
OpenAlex	19