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A Cryptand Metal-Organic Framework as a Platform for the Selective Uptake and Detection of Group I Metal Cations Full article

Journal Chemistry: A European Journal
ISSN: 0947-6539 , E-ISSN: 1521-3765
Output data Year: 2017, Volume: 23, Number: 10, Pages: 2286-2289 Pages count : 4 DOI: 10.1002/chem.201605895
Authors Sapchenko Sergey A. 1,2 , Demakov Pavel A. 1,2 , Samsonenko Denis G. 1,2 , Dybtsev Danil N. 1,2 , Schröder Martin 1,3 , Fedin Vladimir P. 1,2
Affiliations
1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Ave., Novosibirsk, 630090 Russian Federation
2 Department of Natural Sciences, Novosibirsk State University, 2 Pirogova Str., Novosibirsk, 630090 Russian Federation
3 School of Chemistry, University of Manchester, Manchester, M13 9PL UK

Abstract: The metal–organic framework (MOF) complex (H3O)2[Zn4(ur)(Hfdc)2(fdc)4] (1, ur=urotropine, H2fdc=furan-2,5-dicarboxylic acid) incorporates cryptand-like cavities, which can be used to separate and detect Rb+ and Cs+ optically. This is the first example of the effective employment of a MOF material for optical detection of these cations.
Cite: Sapchenko S.A. , Demakov P.A. , Samsonenko D.G. , Dybtsev D.N. , Schröder M. , Fedin V.P.
A Cryptand Metal-Organic Framework as a Platform for the Selective Uptake and Detection of Group I Metal Cations
Chemistry: A European Journal. 2017. V.23. N10. P.2286-2289. DOI: 10.1002/chem.201605895 WOS Scopus РИНЦ OpenAlex
Dates:
Submitted: Dec 19, 2016
Published print: Feb 16, 2017
Identifiers:
Web of science: WOS:000395583200009
Scopus: 2-s2.0-85010223518
Elibrary: 29473560
OpenAlex: W2573307531
Citing:
DB Citing
Web of science 19
Scopus 20
Elibrary 19
OpenAlex 19
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