Synthesis and crystal structure of a luminescent metal-organic framework based on 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole

Synthesis and crystal structure of a luminescent metal-organic framework based on 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2022, Volume: 71, Number: 5, Pages: 974-979 Pages count : 6 DOI: 10.1007/s11172-022-3499-x

Authors

Pavlov D.I. ¹ , Poklonova V.V. ^1,2 , Ryadun A.A. ¹ , Samsonenko D.G. ¹ , Dorovatovskii P.V. ³ , Lazarenko V.A. ³ , Fedin V.P. ¹ , Potapov A.S. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation
2	Novosibirsk State University, 1 ul. Pirogova, 630090, Novosibirsk, Russian Federation
3	National Research Center “Kurchatov Institute”, 1 ul. Akad. Kurchatova, 123182, Moscow, Russian Federation

A three-dimensional coordination polymer was synthesized by the reaction of zinc(ii) nitrate with 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole and di(imidazol-1-yl)methane. The crystal structure of the new compound was determined by single-crystal X-ray diffraction. In the structure of the metal-organic framework, the trinuclear secondary building units are connected to each other to form a uninodal eight-connected net with the symbol {33.418.55.62}. This topology has not been previously found in coordination polymers. The framework contains channels with dimensions of 7×8 Å2. The solvent-accessible volume is 24%. The compound exhibits emission with a maximum at 524 nm upon excitation at 395 nm. The photoluminescence quantum yield is 19%.

Pavlov D.I. , Poklonova V.V. , Ryadun A.A. , Samsonenko D.G. , Dorovatovskii P.V. , Lazarenko V.A. , Fedin V.P. , Potapov A.S.
Synthesis and crystal structure of a luminescent metal-organic framework based on 4,7-(4-carboxyphenyl)-2,1,3-benzoxadiazole
Russian Chemical Bulletin. 2022. V.71. N5. P.974-979. DOI: 10.1007/s11172-022-3499-x WOS Scopus РИНЦ OpenAlex

Павлов Д.И. , Поклонова В.В. , Рядун А.А. , Самсоненко Д.Г. , Дороватовский П.В. , Лазаренко В.А. , Федин В.П. , Потапов А.С.
Синтез и кристаллическая структура люминесцентного металл-органического каркаса на основе 4,7-(4-карбоксифенил)-2,1,3-бензоксадиазола
Известия Академии наук. Серия химическая. 2022. №5. С.974-979.

Submitted:	Dec 15, 2021
Accepted:	Feb 10, 2022
Published online:	May 21, 2022

Web of science:	WOS:000798485000015
Scopus:	2-s2.0-85130331375
Elibrary:	48591203
OpenAlex:	W4281264023

DB	Citing
Web of science	1
Scopus	1
Elibrary	3
OpenAlex	1