Low-dimensional group IV–VII transition metal polychalcogenides and chemical aspects of their applications Review
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Russian Chemical Reviews
ISSN: 1468-4837 , E-ISSN: 0036-021X |
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| Output data | Year: 2023, Volume: 92, Number: 3, Article number : RCR5072, Pages count : 1 DOI: 10.57634/rcr5072 | ||||
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Funding (2)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 121031700321-3 |
| 2 | Russian Science Foundation | 21-13-00274 |
Abstract:
This review systematizes literature data on polymeric polychalcogenides of group IV7VII transition metals (TiS3 , VS4 , NbSe3 , MoSx , ReS4 , etc.). It covers the structural characteristics of crystalline compounds and the proposed structural models of amorphous phases. The latest advances in the synthesis of these low-dimensional materials at the nanoscale are presented. Their chemical properties are discussed, in particular, those arising from the presence of the dichalcogenide bonds. It is emphasized that the properties of the S7S (or Se7Se) groups largely determine the distinctive features of polychalcogenides and the unusual phenomena observed in them. In particular, these groups play an important role in the performance of electrode materials in metal-ion batteries, photo- and electrocatalysts for hydrogen evolution reaction, and mercury vapour sorbents based on transition metal polychalcogenides, which is also addressed in this review.
The bibliography includes 304 references.
Cite:
Grayfer E.D.
, Artemkina S.B.
, Ivanova M.N.
, Brylev K.A.
, Fedorov V.E.
Low-dimensional group IV–VII transition metal polychalcogenides and chemical aspects of their applications
Russian Chemical Reviews. 2023. V.92. N3. RCR5072 :1-1. DOI: 10.57634/rcr5072 WOS Scopus РИНЦ OpenAlex
Low-dimensional group IV–VII transition metal polychalcogenides and chemical aspects of their applications
Russian Chemical Reviews. 2023. V.92. N3. RCR5072 :1-1. DOI: 10.57634/rcr5072 WOS Scopus РИНЦ OpenAlex
Original:
Грайфер Е.Д.
, Артемкина С.Б.
, Иванова М.Н.
, Брылев К.А.
, Федоров В.Е.
Низкоразмерные полихалькогениды переходных металлов IV-VII групп и химические аспекты их применений
Успехи химии. 2023. Т.92. №3. RCR5072 :1-30. DOI: 10.57634/RCR5072RUS РИНЦ
Низкоразмерные полихалькогениды переходных металлов IV-VII групп и химические аспекты их применений
Успехи химии. 2023. Т.92. №3. RCR5072 :1-30. DOI: 10.57634/RCR5072RUS РИНЦ
Dates:
| Submitted: | Nov 1, 2022 |
| Published print: | Mar 24, 2023 |
Identifiers:
| Web of science: | WOS:000991695100003 |
| Scopus: | 2-s2.0-85162767400 |
| Elibrary: | 0409962 |
| OpenAlex: | W4386947829 |