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SYNTHESIS AND STRUCTURES OF COORDINATION POLYMERS BASED ON A BRIDGING LIGAND WITH THE THIENOTHIOPHENE BACKBONE Full article

Journal Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766
Output data Year: 2022, Volume: 63, Number: 2, Pages: 227-234 Pages count : 8 DOI: 10.1134/s0022476622020032
Authors Dubskikh V.A. 1 , Lysova A.A. 1 , Samsonenko D.G. 1 , Dybtsev D.N. 1 , Fedin V.P. 1
Affiliations
1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Abstract: Two novel metal-organic coordination polymers [Sr(ttdc)(dma)2] (1) and [Zn(ttdc)(bpy)]·DMA·4H2O (2) (H2ttdc = thieno[3,2-b]thiophene-2,5-dicarboxylic acid, bpy = 2,2′-bipyridyl, DMA = N,N-dimethylacetamide) are synthesized under solvothermal conditions. Structures of the compounds are established by the single crystal X-ray diffraction (XRD) analysis. The coordination polymers are characterized by powder XRD, elemental and thermogravimetric analyses, and IR spectroscopy. Compound 1 is a 2D coordination polymer while compound 2 is composed of zigzag chains linked by π–π stacking between bpy molecules into a porous supramolecular framework with a free volume of 42%.
Cite: Dubskikh V.A. , Lysova A.A. , Samsonenko D.G. , Dybtsev D.N. , Fedin V.P.
SYNTHESIS AND STRUCTURES OF COORDINATION POLYMERS BASED ON A BRIDGING LIGAND WITH THE THIENOTHIOPHENE BACKBONE
Journal of Structural Chemistry. 2022. V.63. N2. P.227-234. DOI: 10.1134/s0022476622020032 WOS Scopus РИНЦ OpenAlex
Original: Дубских В.А. , Лысова А.А. , Самсоненко Д.Г. , Дыбцев Д.Н. , Федин В.П.
Синтез и строение координационных полимеров на основе мостикового лиганда с тиенотиофеновым остовом
Журнал структурной химии. 2022. Т.63. №2. С.163-170. DOI: 10.26902/jsc_id87114 РИНЦ OpenAlex
Dates:
Submitted: Aug 13, 2021
Accepted: Aug 24, 2021
Published online: Mar 11, 2022
Identifiers:
Web of science: WOS:000767854000003
Scopus: 2-s2.0-85126254864
Elibrary: 48192284
OpenAlex: W4220904705
Citing:
DB Citing
OpenAlex 8
Web of science 6
Scopus 6
Elibrary 6
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