SYNTHESIS AND STRUCTURES OF COORDINATION POLYMERS BASED ON A BRIDGING LIGAND WITH THE THIENOTHIOPHENE BACKBONE Full article
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Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766 |
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Output data | Year: 2022, Volume: 63, Number: 2, Pages: 227-234 Pages count : 8 DOI: 10.1134/s0022476622020032 | ||
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Abstract:
Two novel metal-organic coordination polymers [Sr(ttdc)(dma)2] (1) and [Zn(ttdc)(bpy)]·DMA·4H2O (2) (H2ttdc = thieno[3,2-b]thiophene-2,5-dicarboxylic acid, bpy = 2,2′-bipyridyl, DMA = N,N-dimethylacetamide) are synthesized under solvothermal conditions. Structures of the compounds are established by the single crystal X-ray diffraction (XRD) analysis. The coordination polymers are characterized by powder XRD, elemental and thermogravimetric analyses, and IR spectroscopy. Compound 1 is a 2D coordination polymer while compound 2 is composed of zigzag chains linked by π–π stacking between bpy molecules into a porous supramolecular framework with a free volume of 42%.
Cite:
Dubskikh V.A.
, Lysova A.A.
, Samsonenko D.G.
, Dybtsev D.N.
, Fedin V.P.
SYNTHESIS AND STRUCTURES OF COORDINATION POLYMERS BASED ON A BRIDGING LIGAND WITH THE THIENOTHIOPHENE BACKBONE
Journal of Structural Chemistry. 2022. V.63. N2. P.227-234. DOI: 10.1134/s0022476622020032 WOS Scopus РИНЦ OpenAlex
SYNTHESIS AND STRUCTURES OF COORDINATION POLYMERS BASED ON A BRIDGING LIGAND WITH THE THIENOTHIOPHENE BACKBONE
Journal of Structural Chemistry. 2022. V.63. N2. P.227-234. DOI: 10.1134/s0022476622020032 WOS Scopus РИНЦ OpenAlex
Original:
Дубских В.А.
, Лысова А.А.
, Самсоненко Д.Г.
, Дыбцев Д.Н.
, Федин В.П.
Синтез и строение координационных полимеров на основе мостикового лиганда с тиенотиофеновым остовом
Журнал структурной химии. 2022. Т.63. №2. С.163-170. DOI: 10.26902/jsc_id87114 РИНЦ OpenAlex
Синтез и строение координационных полимеров на основе мостикового лиганда с тиенотиофеновым остовом
Журнал структурной химии. 2022. Т.63. №2. С.163-170. DOI: 10.26902/jsc_id87114 РИНЦ OpenAlex
Dates:
Submitted: | Aug 13, 2021 |
Accepted: | Aug 24, 2021 |
Published online: | Mar 11, 2022 |
Identifiers:
Web of science: | WOS:000767854000003 |
Scopus: | 2-s2.0-85126254864 |
Elibrary: | 48192284 |
OpenAlex: | W4220904705 |