TETRAAMMINOPLATINUM(II) PARAMOLYBDATE. SYNTHESIS, CRYSTAL STRUCTURE, THERMAL PROPERTIES Full article
| Journal |
Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766 |
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| Output data | Year: 2022, Volume: 63, Number: 8, Pages: 1340-1348 Pages count : 9 DOI: 10.1134/s0022476622080157 | ||
| Tags | platinum, molybdenum, paramolybdate, thermal decomposition, solid solution | ||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Science Foundation | 22-23-00672 |
| 2 | Ministry of Science and Higher Education of the Russian Federation | 121031700313-8 |
| 3 | Ministry of Science and Higher Education of the Russian Federation | 121031700315–2 |
Abstract:
The crystal structure of the [Pt(NH3)4]3Mo7O24⋅5.5H2O complex salt is determined for the first time by XRD. Thermal decomposition of this complex in reducing and inert atmospheres is studied. Intermediate and final products of thermal decomposition are determined. It is established that thermolysis in a reducing atmosphere leads to the formation of an ordered solid solution with the intermetallic Mo2Pt3 structure, while the final product of thermolysis in an inert atmosphere is a two-phase mixture of metallic platinum and molybdenum(IV) oxide.
Cite:
Lagunova V.I.
, Filatov E.Y.
, Plyusnin P.E.
, Pervukhina N.V.
, Kuratieva N.V.
, Zadesenets A.V.
, Korenev S.V.
TETRAAMMINOPLATINUM(II) PARAMOLYBDATE. SYNTHESIS, CRYSTAL STRUCTURE, THERMAL PROPERTIES
Journal of Structural Chemistry. 2022. V.63. N8. P.1340-1348. DOI: 10.1134/s0022476622080157 WOS Scopus РИНЦ OpenAlex
TETRAAMMINOPLATINUM(II) PARAMOLYBDATE. SYNTHESIS, CRYSTAL STRUCTURE, THERMAL PROPERTIES
Journal of Structural Chemistry. 2022. V.63. N8. P.1340-1348. DOI: 10.1134/s0022476622080157 WOS Scopus РИНЦ OpenAlex
Original:
Лагунова В.И.
, Филатов Е.Ю.
, Плюснин П.Е.
, Первухина Н.В.
, Куратьева Н.В.
, Задесенец А.В.
, Коренев С.В.
ПАРАМОЛИБДАТ ТЕТРААММИНПЛАТИНЫ(II). СИНТЕЗ, КРИСТАЛЛИЧЕСКАЯ СТРУКТУРА, ТЕРМИЧЕСКИЕ СВОЙСТВА
Журнал структурной химии. 2022. Т.63. №8. 97272 :1-9. DOI: 10.26902/JSC_id97272 РИНЦ OpenAlex
ПАРАМОЛИБДАТ ТЕТРААММИНПЛАТИНЫ(II). СИНТЕЗ, КРИСТАЛЛИЧЕСКАЯ СТРУКТУРА, ТЕРМИЧЕСКИЕ СВОЙСТВА
Журнал структурной химии. 2022. Т.63. №8. 97272 :1-9. DOI: 10.26902/JSC_id97272 РИНЦ OpenAlex
Dates:
| Submitted: | Apr 1, 2022 |
| Accepted: | Apr 14, 2022 |
| Published print: | Aug 1, 2022 |
Identifiers:
| Web of science: | WOS:000848768400015 |
| Scopus: | 2-s2.0-85137489988 |
| Elibrary: | 51639914 |
| OpenAlex: | W4294145544 |