DOUBLE COMPLEX SALTS OF NICKEL AMINES WITH THE [RuNOCl5]2– ANION: SYNTHESIS, STRUCTURE, PROPERTIES Full article
| Journal |
Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766 |
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| Output data | Year: 2022, Volume: 63, Number: 12, Pages: 1973-1980 Pages count : 8 DOI: 10.1134/s0022476622120083 | ||
| Tags | ruthenium nitroso complexes, double complex salts, thermal analysis, metastable nanoalloys | ||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Science Foundation | 21-73-20203 |
| 2 | Ministry of Science and Higher Education of the Russian Federation | 121031700313-8 |
| 3 | Ministry of Science and Higher Education of the Russian Federation | 121031700315–2 |
Abstract:
Two new double complex salts [Ni(NH3)6][RuNOCl5] and [Ni(en)3][RuNOCl5] are prepared and structurally characterized. The structure of both compounds is formed by [Ni(NH3)6]2+ and [Ni(en)3]2+ cations and [RuNOCl5]2– anions. The cation and anion polyhedra form alternating cation–anion columns in the [Ni(en)3][RuNOCl5] structure and the CsCl type packing in the [Ni(NH3)6][RuNOCl5] structure. The interaction between cation and anion sublattices is mostly electrostatic in both compounds. Thermolysis of these compounds in a reducing atmosphere leads to the formation of metastable Ni–Ru solid solutions. Thermal degradation of [Ni(en)3][RuNOCl5] begins with the Anderson rearrangements.
Cite:
Borodin A.O.
, Kuratieva N.V.
, Plyusnin P.E.
, Filatov E.Y.
, Korenev S.V.
, Kostin G.A.
DOUBLE COMPLEX SALTS OF NICKEL AMINES WITH THE [RuNOCl5]2– ANION: SYNTHESIS, STRUCTURE, PROPERTIES
Journal of Structural Chemistry. 2022. V.63. N12. P.1973-1980. DOI: 10.1134/s0022476622120083 WOS Scopus OpenAlex
DOUBLE COMPLEX SALTS OF NICKEL AMINES WITH THE [RuNOCl5]2– ANION: SYNTHESIS, STRUCTURE, PROPERTIES
Journal of Structural Chemistry. 2022. V.63. N12. P.1973-1980. DOI: 10.1134/s0022476622120083 WOS Scopus OpenAlex
Original:
Бородин А.О.
, Куратьева Н.В.
, Плюснин П.Е.
, Филатов Е.Ю.
, Коренев С.В.
, Костин Г.А.
ДВОЙНЫЕ КОМПЛЕКСНЫЕ СОЛИ АМИНОВ НИКЕЛЯ С АНИОНОМ [RuNOCl5]2–: СИНТЕЗ, СТРУКТУРА, СВОЙСТВА
Журнал структурной химии. 2022. Т.63. №12. 102948 :1-8. DOI: 10.26902/JSC_id102948 РИНЦ OpenAlex
ДВОЙНЫЕ КОМПЛЕКСНЫЕ СОЛИ АМИНОВ НИКЕЛЯ С АНИОНОМ [RuNOCl5]2–: СИНТЕЗ, СТРУКТУРА, СВОЙСТВА
Журнал структурной химии. 2022. Т.63. №12. 102948 :1-8. DOI: 10.26902/JSC_id102948 РИНЦ OpenAlex
Dates:
| Submitted: | Sep 9, 2022 |
| Accepted: | Sep 28, 2022 |
| Published print: | Dec 1, 2022 |
Identifiers:
| Web of science: | WOS:000905664400008 |
| Scopus: | 2-s2.0-85145381794 |
| OpenAlex: | W4313417614 |