Formation of Platinum Tetrachloride from Hexachloroplatinates(IV) Full article
| Journal |
Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613 |
||
|---|---|---|---|
| Output data | Year: 2022, Volume: 67, Number: 12, Pages: 1919-1927 Pages count : 9 DOI: 10.1134/s0036023622601362 | ||
| Tags | platinum, chloro complexes, chlorides, sulfuric acid | ||
| Authors |
|
||
| Affiliations |
|
Funding (1)
| 1 | Russian Science Foundation | 21-73-10038 |
Abstract:
A new method for the synthesis of platinum(IV) chloride has been developed based on the interaction of concentrated sulfuric acid (96 wt %) with alkali metal hexachloroplatinates(IV) at a temperature of 160°C. It has been shown that the yield of platinum chloride (α-PtCl4) is at least 95%, and the main by-products that remain in the sulfuric acid solution are platinum(IV) chloroaqua and sulfate-chloroaqua complexes. The resulting α-PtCl4 compound has been studied in detail using X-ray powder diffraction and thermogravimetric analysis, nuclear magnetic resonance spectroscopy (195Pt magic angle spinning NMR), and Raman spectroscopy.
Cite:
Vasilchenko D.B.
, Komarov V.Y.
, Tkachev S.V.
, Plusnin P.E.
, Filatov E.Y.
Formation of Platinum Tetrachloride from Hexachloroplatinates(IV)
Russian Journal of Inorganic Chemistry. 2022. V.67. N12. P.1919-1927. DOI: 10.1134/s0036023622601362 WOS Scopus OpenAlex
Formation of Platinum Tetrachloride from Hexachloroplatinates(IV)
Russian Journal of Inorganic Chemistry. 2022. V.67. N12. P.1919-1927. DOI: 10.1134/s0036023622601362 WOS Scopus OpenAlex
Original:
Васильченко Д.Б.
, Комаров В.Ю.
, Ткачев С.В.
, Плюснин П.Е.
, Филатов Е.Ю.
ОБРАЗОВАНИЕ ТЕТРАХЛОРИДА ПЛАТИНЫ ИЗ ГЕКСАХЛОРОПЛАТИНАТОВ(IV)
Журнал неорганической химии. 2022. Т.67. №12. С.1707–1716. DOI: 10.31857/S0044457X22601018 РИНЦ OpenAlex
ОБРАЗОВАНИЕ ТЕТРАХЛОРИДА ПЛАТИНЫ ИЗ ГЕКСАХЛОРОПЛАТИНАТОВ(IV)
Журнал неорганической химии. 2022. Т.67. №12. С.1707–1716. DOI: 10.31857/S0044457X22601018 РИНЦ OpenAlex
Dates:
| Submitted: | Jun 23, 2022 |
| Accepted: | Jul 8, 2022 |
| Published print: | Dec 1, 2022 |
Identifiers:
| Web of science: | WOS:000921525000003 |
| Scopus: | 2-s2.0-85144577044 |
| OpenAlex: | W4312080458 |