Formation of Platinum Tetrachloride from Hexachloroplatinates(IV)

Formation of Platinum Tetrachloride from Hexachloroplatinates(IV) Full article

Journal

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613

Output data

Year: 2022, Volume: 67, Number: 12, Pages: 1919-1927 Pages count : 9 DOI: 10.1134/s0036023622601362

Funding (1)

Russian Science Foundation

21-73-10038

A new method for the synthesis of platinum(IV) chloride has been developed based on the interaction of concentrated sulfuric acid (96 wt %) with alkali metal hexachloroplatinates(IV) at a temperature of 160°C. It has been shown that the yield of platinum chloride (α-PtCl4) is at least 95%, and the main by-products that remain in the sulfuric acid solution are platinum(IV) chloroaqua and sulfate-chloroaqua complexes. The resulting α-PtCl4 compound has been studied in detail using X-ray powder diffraction and thermogravimetric analysis, nuclear magnetic resonance spectroscopy (195Pt magic angle spinning NMR), and Raman spectroscopy.

Vasilchenko D.B. , Komarov V.Y. , Tkachev S.V. , Plusnin P.E. , Filatov E.Y.
Formation of Platinum Tetrachloride from Hexachloroplatinates(IV)
Russian Journal of Inorganic Chemistry. 2022. V.67. N12. P.1919-1927. DOI: 10.1134/s0036023622601362 WOS Scopus OpenAlex

Васильченко Д.Б. , Комаров В.Ю. , Ткачев С.В. , Плюснин П.Е. , Филатов Е.Ю.
ОБРАЗОВАНИЕ ТЕТРАХЛОРИДА ПЛАТИНЫ ИЗ ГЕКСАХЛОРОПЛАТИНАТОВ(IV)
Журнал неорганической химии. 2022. Т.67. №12. С.1707–1716. DOI: 10.31857/S0044457X22601018 РИНЦ OpenAlex

Submitted:	Jun 23, 2022
Accepted:	Jul 8, 2022
Published print:	Dec 1, 2022

Web of science:	WOS:000921525000003
Scopus:	2-s2.0-85144577044
OpenAlex:	W4312080458

Пока нет цитирований