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Metal-mediated tunability of MOF-based optical modulators Full article

Journal Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X
Output data Year: 2023, Volume: 59, Number: 66, Pages: 9964-9967 Pages count : 4 DOI: 10.1039/d3cc02180g
Authors Kulachenkov Nikita K. 1 , Orlioglo Bogdan 2 , Vasilyev Eugene S. 3 , Povarov Svyatoslav A. 1 , Agafontsev Alexander M. 3,4 , Bachinin Semyon 1 , Shipilovskikh Sergei 1 , Lunev Artem 1 , Samsonenko Denis G. 5 , Fedin Vladimir P. 5 , Kovalenko Konstantin A. 5 , Milichko Valentin A. 1,6
Affiliations
1 School of Physics and Engineering, ITMO University, St. Petersburg, Russia
2 Chemical Science Program, KAUST Catalysis Center, Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, Saudi Arabia
3 Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9 Acad. Lavrentiev Ave., Novosibirsk 630090, Russia
4 Novosibirsk State University, 2 Pirogova St., Novosibirsk 630090, Russia
5 Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Akad. Lavrentiev Ave., Novosibirsk 630090, Russia
6 Universit de Lorraine, UMR CNRS 7198, Nancy 54011, France

Funding (3)

1 Ministry of Science and Higher Education of the Russian Federation 121031700321-3
2 Russian Science Foundation 18-73-00148
3 Russian Science Foundation 22-72-10027

Abstract: We report on the design of 1D MOFs based on a nopinane-annelated organic ligand and Co(II) or Ni(II), the variation of which allows tuning the optical modulation bandwidth. Structural and time-resolved analysis revealed the optical modulation mechanism, the rates and its endurance, thereby enriching the list of sustainable MOFs for tunable optical modulators.
Cite: Kulachenkov N.K. , Orlioglo B. , Vasilyev E.S. , Povarov S.A. , Agafontsev A.M. , Bachinin S. , Shipilovskikh S. , Lunev A. , Samsonenko D.G. , Fedin V.P. , Kovalenko K.A. , Milichko V.A.
Metal-mediated tunability of MOF-based optical modulators
Chemical Communications. 2023. V.59. N66. P.9964-9967. DOI: 10.1039/d3cc02180g WOS Scopus OpenAlex
Dates:
Submitted: May 9, 2023
Accepted: Jul 14, 2023
Published print: Jul 17, 2023
Identifiers:
Web of science: WOS:001037419200001
Scopus: 2-s2.0-85167461034
OpenAlex: W4384570559
Citing:
DB Citing
Web of science 6
Scopus 8
OpenAlex 11
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