Heteroleptic Palladium(II) Complexes with Aromatic Acceptor Diimines

Heteroleptic Palladium(II) Complexes with Aromatic Acceptor Diimines Full article

Journal

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Output data

Year: 2026, Number: 67, Pages: 1573-1581 Pages count : 9 DOI: 10.1134/S0022476626070139

Authors

Romashev N.F. ¹ , Komlyagina V.I. ¹ , Bakaev I.V. ¹ , Chekhov E.V. ^1,2 , Gukova A.K. ^1,2 , Gorshkov A.P. ^1,2 , Gushchin A.L. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia

Mixed ligand complexes [Pd(dpp-bian)(PhenQ)](CF3SO3)2 (1) and [Pd(tmp-bian)(PhenQ)](CF3SO3)2 (2) are synthesized by the interaction of [Pd(dpp-bian)Cl2] (dpp-bian – 1,2-bis-{(2,6-diisopropylphenyl)imino}acenaphthene) and [Pd(tmp-bian)Cl2] (tmp-bian – 1,2-bis-{(2,4,6-trimethylphenyl)imino}acenaphthene) with 1,10-phenanthroline-4,5-dione (phenanthroline quinone, PhenQ) in the presence of silver triflate. The obtained compounds are characterized by the elemental analysis and 1H NMR spectroscopy. Molecular and crystal structures of 1 CH2Cl2 and 2 Et2O are determined by the single crystal X-ray diffraction analysis. The electrochemical properties are analyzed by cyclic voltammetry.

Romashev N.F. , Komlyagina V.I. , Bakaev I.V. , Chekhov E.V. , Gukova A.K. , Gorshkov A.P. , Gushchin A.L.
Heteroleptic Palladium(II) Complexes with Aromatic Acceptor Diimines
Journal of Structural Chemistry. 2026. N67. P.1573-1581. DOI: 10.1134/S0022476626070139 WOS Scopus

Ромашев Н.Ф. , Комлягина В.И. , Бакаев И.В. , Чехов Е.В. , Гукова А.К. , Горшков А.П. , Гущин А.Л.
Гетеролептические комплексы палладия(II) с ароматическими акцепторными дииминами
Журнал структурной химии. 2026. Т.67. №7. 169219 :1-9. DOI: 10.26902/jsc_id169219

Submitted:	Apr 3, 2026
Accepted:	Apr 20, 2026
Published print:	Jul 30, 2026

≡ Web of science:	WOS:001838378800004
≡ Scopus:	2-s2.0-105046326205