Iodide-to-DMSO substitution in [{M6I8}I6] (M = Mo, W) clusters: NMR-resolved isomeric pathway and isolation of early adducts

Iodide-to-DMSO substitution in [{M6I8}I6] (M = Mo, W) clusters: NMR-resolved isomeric pathway and isolation of early adducts Full article

Journal

Journal of Molecular Structure
ISSN: 0022-2860 , E-ISSN: 1872-8014

Output data

Year: 2026, Volume: 1370, Article number : 146446, Pages count : 12 DOI: 10.1016/j.molstruc.2026.146446

Tags

Cluster complexes, Molybdenum, Tungsten, Dimethyl sulfoxide, Crystal structure, Heteroleptic complexes, Luminescence

Authors

Petunin Anton A. ¹ , Evtushok Darya V. ¹ , Vegner Margarita V. ¹ , Berezin Alexey S. ¹ , Sukhikh Taisiya S. ¹ , Eltsov Ilia V. ² , Shestopalov Michael A. ¹ , Vorotnikov Yuri A. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry SB RAS, 3 acad. Lavrentiev ave. 630090, Novosibirsk, Russia
2	Novosibirsk State University, 1 Pirogova St. 630090, Novosibirsk, Russia

Funding (1)

Petunin A.A. , Evtushok D.V. , Vegner M.V. , Berezin A.S. , Sukhikh T.S. , Eltsov I.V. , Shestopalov M.A. , Vorotnikov Y.A.
Iodide-to-DMSO substitution in [{M6I8}I6] (M = Mo, W) clusters: NMR-resolved isomeric pathway and isolation of early adducts
Journal of Molecular Structure. 2026. V.1370. 146446 :1-12. DOI: 10.1016/j.molstruc.2026.146446 Scopus OpenAlex

Submitted:	Jan 23, 2026
Accepted:	May 1, 2026
Published online:	May 2, 2026
Published print:	Sep 15, 2026

≡ Scopus:	2-s2.0-105037975721
≡ OpenAlex:	W7160291242