Synthesis and structure of [Sb(µ2-O)Cl(DMSO-О)]n

Synthesis and structure of [Sb(µ2-O)Cl(DMSO-О)]n Full article

Journal

INEOS OPEN
ISSN: 2658-5618

Output data

Year: 2025, Volume: 8, Number: 1-3, Pages: 52-53 Pages count : 2 DOI: 10.32931/io2515a

Tags

triarylstibine, hydrochloric acid, dimethyl sulfoxide, Lewis acid, structure, synthesis

Authors

Egorova I.V. ¹ , Nesina I.N. ¹ , Zhidkov V.V. ¹ , Rodionova N.A. ¹ , Kuratieva N.V. ² , Pervukhina N.V. ²

Affiliations

1	Blagoveshchensk State Pedagogical University, Blagoveshchensk, ul. Lenina 104, 675004 Russia
2	Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, pr. Akademika Lavrent'eva 3, Novosibirsk, 630090 Russia

New complex [Sb(2-O)Cl(DMSO-О)]n was obtained by the interaction of tris(2,6-dimethoxyphenyl)stibine with HCl in chloroform followed by the recrystallization of the product from DMSO. X-ray diffraction analysis revealed a distorted trigonal bipyramidal bisphenoidal environment of the antimony atoms, with the axial angles O–Sb–Cl of 163.8(3), 164.1(3)° and the interatomic distances 2-O–Sb and Sb–Oax of 1.948(9), 1.973(9) Å and 2.242(10), 2.194(11) Å, respectively.

Egorova I.V. , Nesina I.N. , Zhidkov V.V. , Rodionova N.A. , Kuratieva N.V. , Pervukhina N.V.
Synthesis and structure of [Sb(µ2-O)Cl(DMSO-О)]n
INEOS OPEN. 2025. V.8. N1-3. P.52-53. DOI: 10.32931/io2515a OpenAlex

Submitted:	Oct 18, 2024
Accepted:	Jan 17, 2025
Published print:	Aug 26, 2025

OpenAlex:

W4412697798

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