Реферат: New bimetallic complexes of the composition [MHg(C6H6N2O)2(SCN)4] have been synthesized,where M = Mn2+ (I), Fe2+ (II), Cd2+ (III) and С6H6N2O is nicotinamide (NA). The compounds were obtained from aqueous solutions and studied by CHNS/O analysis, IR spectroscopy, inductively coupled plasma optical emission spectrometry (ICP-OES), and single-crystal X-ray diffraction. Compounds I–III are isostructural and crystallize in the monoclinic syngony (space group C2/c). The coordination environment of the M2+ atom is formed by two donor nitrogen atoms of two monodentately coordinated NA and four nitrogen atoms of the SCN groups, which form bridges between the M2+ and Hg2+ ions, connecting them into a three-dimensional framework. Hg2+ ions have a tetrahedral coordination environment consisting of four S atoms of four SCN groups.

Библиографическая ссылка: Barantsev D.A. , Pervukhina N.V. , Kuratieva N.V. , Cherkasova T.G.
Synthesis and Crystal Structures of Framework Tetrarhodanomercurate Mn(II), Fe(II), and Cd(II) Complexes with Nicotinamide
Russian Journal of Inorganic Chemistry. 2025. V.70. N8. P.1179-1183. DOI: 10.1134/S0036023625601357 WOS

Оригинальная: Баранцев Д.А. , Первухина Н.В. , Куратьева Н.В. , Черкасова Т.Г.
КАРКАСНЫЕ ТЕТРАРОДАНОМЕРКУРАТНЫЕ КОМПЛЕКСЫ Mn(II), Fe(II), Cd(II) С НИКОТИНАМИДОМ: СИНТЕЗ И КРИСТАЛЛИЧЕСКОЕ СТРОЕНИЕ
Журнал неорганической химии. 2025. Т.70. №8. С.1046–1050. DOI: 10.31857/S0044457X25080087 РИНЦ

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Опубликована в печати:

30 сент. 2025 г.

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WOS:001586139100011

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