Structure of Heterobimetallic β-Diketonates Formed by Platinum(II) Acetylacetonate and Lead(II) Hexafluoroacetylacetonate

Structure of Heterobimetallic β-Diketonates Formed by Platinum(II) Acetylacetonate and Lead(II) Hexafluoroacetylacetonate Full article

Journal

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Output data

Year: 2025, Volume: 66, Pages: 1942–1950 Pages count : DOI: 10.1134/S0022476625090161

Authors

Krisyuk V.V. ¹ , Baidina I.A. ¹ , Korolkov I.V. ¹ , Turgambaeva A.E. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

New platinum(II) acetylacetonate and lead(II) hexafluoroacetylacetonate heterometallic complexes, [(Pt(acac)2)5(Pb(hfac)2)4] (1) and [Pt(acac)2Pb(hfac)2] (2), are prepared and characterized. Crystal data for 1: a = 13.8795(6) Å, b = 15.0201(6) Å, c = 17.2442(7) Å, α = 105.6503(14)°, β = 110.7887(14)°, γ = 99.0552(14)°, space group, Z = 4, dcalc = 2.380 g/cm3; for 2 a = 16.810(6) Å, b = 30.960(12) Å, c = 18.260(7) Å, β = 105.19(2)°, C2/c space group, Z = 16, dcalc = 2.204 g/cm3. The main structural motifs of these compounds are same-type 1D coordination polymers stabilized by Pt⋯Pt and Pb–O contacts.

Krisyuk V.V. , Baidina I.A. , Korolkov I.V. , Turgambaeva A.E.
Structure of Heterobimetallic β-Diketonates Formed by Platinum(II) Acetylacetonate and Lead(II) Hexafluoroacetylacetonate
Journal of Structural Chemistry. 2025. V.66. P.1942–1950. DOI: 10.1134/S0022476625090161 WOS

Крисюк В.В. , Байдина И.А. , Корольков И.В. , Тургамбаева А.Е.
Структура гетеробиметаллических β-дикетонатов, образованных ацетилацетонатом платины(II) и гексафторацетилацетонатом свинца(II)
Журнал структурной химии. 2025. Т.66. №9. 152314 . DOI: 10.26902/JSC_id152314

Published print:

Oct 9, 2025

Web of science:

WOS:001591583400018

Пока нет цитирований