Luminescent cyanide coordination polymer based on {Mo6I8} and {Ag2(dppm)2} clusters: exceptional stability and efficient scintillation

Luminescent cyanide coordination polymer based on {Mo6I8} and {Ag2(dppm)2} clusters: exceptional stability and efficient scintillation Научная публикация

Журнал

Inorganic chemistry frontiers
ISSN: 2052-1553 , E-ISSN: 2052-1545

Вых. Данные

Год: 2025, Том: 24, Страницы: 8536-8546 Страниц : 11 DOI: 10.1039/D5QI01532D

Авторы

Litvinova Yulia M. ¹ , Stass Dmitri V. ^2,3 , Metlin Mikhail T. ^4,5 , Korshunov Vladislav M. ⁴ , Ryzhikov Maxim R. ¹ , Yarovoy Spartak S. ¹ , Sukhikh Taisiya S. ¹ , Mironov Yuri V. ¹ , Taydakov Ilya V. ⁴ , Belikova Daria E. ⁶ , Tarasov Alexey B. ^6,7 , Brylev Konstantin A. ¹ , Gaifulin Yakov M. ¹

Организации

1	Nikolaev Institute of Inorganic Chemistry SB RAS
2	Voevodsky Institute of Chemical Kinetics and Combustion SB RAS
3	Novosibirsk State University
4	Lebedev Physical Institute RAS
5	Bauman Moscow State Technical University
6	Laboratory of New Materials for Solar Energetics, Faculty of Materials Science, Lomonosov Moscow State University
7	Department of Chemistry, Lomonosov Moscow State University

First metal-organic coordination polymer based on [{Mo6I8}(CN)6]2– cluster anion was obtained using salts Cs1.3Na0.7[{Mo6I8}(CN)6]·2H2O (1) and K[Ag(CN)2], as well as bis(diphenylphosphino)methane (dppm) as precursors. In contrast to the previously reported coordination polymers based on octahedral cyanide cluster complexes, the 1D polymer [{Ag2(dppm)2}{Mo6I8}(CN)6] (2) demonstrated an order of magnitude increase in the cluster-centred photoluminescence quantum yield (Φem) in the solid state at 300 K in comparison with the ionic salt 1. Moreover, 2 displays bright X-ray induced emission, which is two orders of magnitude more intense than that of 1 and is characterized by a light yield of 10800 photons/MeV. Therefore, 2 represents the first effective scintillating compound, which is based on octahedral molybdenum clusters. The polymer have exceptional thermal, photo- and hydrolytic stability and displays minimal degradation upon Xray irradiation, retaining its emission intensity following exposure to an air-equivalent dose of 2·103 Gray. It should be noted that no compounds based on octahedral molybdenum clusters have been previously obtained that would remain stable when exposed to such radiation doses. The high light yield and exceptional stability of the compound have enabled us to use it to manufacture scintillation screens for X-ray visualisation. These screens have a spatial resolution of up to 9 line pairs/mm, representing the first example of a scintillation device based on octahedral metal clusters.

Litvinova Y.M. , Stass D.V. , Metlin M.T. , Korshunov V.M. , Ryzhikov M.R. , Yarovoy S.S. , Sukhikh T.S. , Mironov Y.V. , Taydakov I.V. , Belikova D.E. , Tarasov A.B. , Brylev K.A. , Gaifulin Y.M.
Luminescent cyanide coordination polymer based on {Mo6I8} and {Ag2(dppm)2} clusters: exceptional stability and efficient scintillation
Inorganic chemistry frontiers. 2025. V.24. P.8536-8546. DOI: 10.1039/D5QI01532D WOS

Поступила в редакцию:	18 июл. 2025 г.
Принята к публикации:	3 сент. 2025 г.
Опубликована online:	15 сент. 2025 г.
Опубликована в печати:	21 дек. 2025 г.

Web of science:

WOS:001578258400001

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