Conformational Dynamics and Thermosensory Properties of [Ln(H2O)n(EDTA)]– (Ln = Pr, Eu, Tb, Ho, Er, Tm) Complexes in Aqueous Solutions according to NMR Data

Conformational Dynamics and Thermosensory Properties of [Ln(H2O)n(EDTA)]– (Ln = Pr, Eu, Tb, Ho, Er, Tm) Complexes in Aqueous Solutions according to NMR Data Full article

Journal

Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613

Output data

Year: 2022, Volume: 67, Number: 11, Pages: 1831-1837 Pages count : 7 DOI: 10.1134/s0036023622601064

Authors

Zapolotsky E.N. ¹ , Babailov S.P. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry SB RAS, 630090, Novosibirsk, Russia

The paramagnetic, thermosensory, and molecular dynamic properties of the [Ln(H2O)n(EDTA)]– (Ln = Pr, Eu, Tb, Ho, Er, Tm) complexes were studied by 1H NMR. The maximum temperature sensitivity of paramagnetic chemical shifts d(δexp)/dT turned out to be 0.48 ppm/K for the Tb complex. It was found that the intramolecular dynamics is due to the inversion of the ethylene cycle and the concerted reorientation of the acetate groups. The value of the activation barrier found for the europium complex turned out to be = 49 ± 3 kJ/mol. The [Ln(H2O)n(EDTA)]– complexes can be considered as promising compounds for the design of thermosensitive NMR probes aimed at determining the local temperature in aqueous media.

Zapolotsky E.N. , Babailov S.P.
Conformational Dynamics and Thermosensory Properties of [Ln(H2O)n(EDTA)]– (Ln = Pr, Eu, Tb, Ho, Er, Tm) Complexes in Aqueous Solutions according to NMR Data
Russian Journal of Inorganic Chemistry. 2022. V.67. N11. P.1831-1837. DOI: 10.1134/s0036023622601064

No identifiers

Пока нет цитирований