Structure of Sodium and Calcium Metal-Organic Frameworks with 2,2'-Diiodobiphenyl-4,4'-dicarboxylic Acid Anions

Structure of Sodium and Calcium Metal-Organic Frameworks with 2,2'-Diiodobiphenyl-4,4'-dicarboxylic Acid Anions Full article

Journal

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Output data

Year: 2025, Volume: 51, Number: 4, Pages: 255-262 Pages count : 8 DOI: 10.1134/S1070328425600147

Authors

Bondarenko M.A. ¹ , Korobeinikov N.A. ¹ , Zaguzin A.S. ¹ , Red’kin R.V. ^1,2 , Pilyukova E.A. ^1,2 , Zaitsev A.V. ^1,2 , Adonin S.A. ^1,3

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2	Novosibirsk National Research State University, Novosibirsk, 630090 Russia
3	Federal Research Center Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, 664033 Russia

The heteroleptic metal-organic frameworks {[Na(μ2-DMF)(HBpdc-I2)]}n (I) and {[Ca(DMF)2(Bpdc-I2)]} (II) were obtained by the reaction of sodium (NaOH) and calcium hydroxides (Ca(OH)2), respectively, with 2,2'-diiodobiphenyl-4,4'-dicarboxylic acid (H2(Bpdc-I2)) in N,N-dimethylformamide (DMF). The product structures were determined by X-ray diffraction. The compounds had two- and three-dimensional structures, respectively. A halogen bond was detected in I between the neighboring Bdc-I2 ligands.

Bondarenko M.A. , Korobeinikov N.A. , Zaguzin A.S. , Red’kin R.V. , Pilyukova E.A. , Zaitsev A.V. , Adonin S.A.
Structure of Sodium and Calcium Metal-Organic Frameworks with 2,2'-Diiodobiphenyl-4,4'-dicarboxylic Acid Anions
Russian Journal of Coordination Chemistry. 2025. V.51. N4. P.255-262. DOI: 10.1134/S1070328425600147

Submitted:	Jan 29, 2025
Accepted:	Mar 3, 2025
Published print:	Jul 10, 2025

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