Thermodynamic study of bromine evaporation from solid Bi(III) polybromides | Sciact

Thermodynamic study of bromine evaporation from solid Bi(III) polybromides Научная публикация

Журнал

The Journal of Chemical Thermodynamics
ISSN: 1096-3626 , E-ISSN: 0021-9614

Вых. Данные

Год: 2020, Том: 141, Номер статьи : 105958, Страниц : 5 DOI: 10.1016/j.jct.2019.105958

Ключевые слова

Bi(III) polybromides Static method with glass membrane-gauge manometers Vapor pressure measurements Enthalpy and entropy of bromine evaporation processes

Авторы

Zelenina L.N. ^1,2 , Chusova T.P. ¹ , Isakov A.V. ¹ , Adonin S.A. ^1,2,3,4 , Sokolov M.N. ^1,2

Организации

1	Nikolaev Institute of Inorganic Chemistry
2	Novosibirsk State University
3	Tobolsk Industrial Institute (Branch of Tyumen Industrial University)
4	South Ural State University,

The pressure of saturated and unsaturated bromine vapor over solid Bi(III) polybromides (PyH)3[Bi2Br9(Br2)] and (N-MePy)3[Bi2Br9(Br2)], where Py is pyridinium, N-MePy is N-methil pyridinium, has been measured for the first time in a wide temperature range using a static method with glass membrane-gauge manometers. As a result of this study the thermal stabilities of investigated complexes were established, the temperature dependences of bromine vapor pressure were obtained, the thermodynamic characteristics of bromine evaporation processes (DprH T, DprS T) were calculated and a new possibility for the synthesis of polybromides was proposed.

Zelenina L.N. , Chusova T.P. , Isakov A.V. , Adonin S.A. , Sokolov M.N.
Thermodynamic study of bromine evaporation from solid Bi(III) polybromides
The Journal of Chemical Thermodynamics. 2020. V.141. 105958 :1-5. DOI: 10.1016/j.jct.2019.105958 WOS OpenAlex

Поступила в редакцию:	30 апр. 2019 г.
Принята к публикации:	14 сент. 2019 г.
Опубликована online:	16 сент. 2019 г.

Web of science:	WOS:000499062100029
OpenAlex:	W2973581028

БД	Цитирований
OpenAlex	7