Acceleration of the thermal decomposition of RDX in microdropletsinvestigated by aerodynamic thermal breakup droplet ionization massspectrometry

Acceleration of the thermal decomposition of RDX in microdropletsinvestigated by aerodynamic thermal breakup droplet ionization massspectrometry Full article

Journal

Aerosol Science and Technology
ISSN: 1521-7388 , E-ISSN: 0278-6826

Output data

Year: 2021, Volume: 55, Number: 3, Pages: 243-253 Pages count : 11 DOI: 10.1080/02786826.2020.1837341

Authors

Pervukhin V.V. ¹ , Sheven D.G. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry of SB RAS, Novosibirsk, Russia

The thermal decomposition of RDX in microdroplets in the heated capillary was investigated by Aerodynamic Thermal Breakup Droplet Ionization (ATBDI) mass spectrometry. The kinetic parameters of the thermal decomposition of RDX in water droplets were estimated. The suction capillary of the ATBDI setup was considered as a flow reactor of ideal displacement. In water droplets, the activation energy of the reaction turns out to be 2-4 times smaller than in the gas and bulk solution, indicating the catalytic role of droplets.

Pervukhin V.V. , Sheven D.G.
Acceleration of the thermal decomposition of RDX in microdropletsinvestigated by aerodynamic thermal breakup droplet ionization massspectrometry
Aerosol Science and Technology. 2021. V.55. N3. P.243-253. DOI: 10.1080/02786826.2020.1837341 WOS OpenAlex

Web of science:	WOS:000586958300001
OpenAlex:	W3096066259

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