Amorphous pentasulfides MS5 (M = Mo, W) in reactions with thiuram disulfide and halogens

Amorphous pentasulfides MS5 (M = Mo, W) in reactions with thiuram disulfide and halogens Full article

Journal

Inorganica Chimica Acta
ISSN: 1873-3255 , E-ISSN: 0020-1693

Output data

Year: 2020, Volume: 512, Article number : 119875, Pages count : 7 DOI: 10.1016/j.ica.2020.119875

Tags

Amorphous metal polysulﬁdes Molybdenum pentasulﬁde Tungsten pentasulﬁde Dithiocarbamate ligand Triangular cluster complex Crystal structure

Authors

Artemkina Sofya ^1,2 , Poltarak Anastasiia ¹ , Poltarak Pavel ¹ , Grayfer Ekaterina ¹ , Samsonenko Denis ^1,2 , Fedorov Vladimir ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry SB RAS, 630090 Novosibirsk, Russia
2	Novosibirsk State University, 630090 Novosibirsk, Russia

Amorphous pentasulﬁdes MoS 5 and WS 5 were studied in a series of chemical reactions for the ﬁrst time. Interaction of MoS 5 and WS 5 with melt of tetramethylthiuramdisulﬁde resulted in two new molecular com- plexes, [{Mo 3 S 7 }(dtc) 3 ](S 3 H) and [{W 3 S 4 }(dtc) 4 (Me 2 NCHS)]. Halogenation of MoS 5 and WS 5 resulted in cluster coordination polymers M 3 S 7 Hal 4 (M = Mo, W; Hal = Cl, Br).

Artemkina S. , Poltarak A. , Poltarak P. , Grayfer E. , Samsonenko D. , Fedorov V.
Amorphous pentasulfides MS5 (M = Mo, W) in reactions with thiuram disulfide and halogens
Inorganica Chimica Acta. 2020. V.512. 119875 :1-7. DOI: 10.1016/j.ica.2020.119875 WOS Scopus РИНЦ OpenAlex

Web of science:	WOS:000571108200017
Scopus:	2-s2.0-85088378834
Elibrary:	45431279
OpenAlex:	W3043355221

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