Novel Three-Dimensional Coordination Polymers Based on [Mo6Se8(CN)6]7− Anions and Mn2+ Cations

Novel Three-Dimensional Coordination Polymers Based on [Mo6Se8(CN)6]7− Anions and Mn2+ Cations Full article

Journal

Journal of Cluster Science
ISSN: 1040-7278 , E-ISSN: 1572-8862

Output data

Year: 2009, Volume: 20, Number: 1, Pages: 165-176 Pages count : 12 DOI: 10.1007/s10876-008-0215-4

Authors

Brylev Konstantin A. ¹ , Naumov Nikolay G. ¹ , Virovets Alexander V. ¹ , Kim Sung-Jin ² , Fedorov Vladimir E. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry; Siberian Branch of the Russian Academy of Sciences
2	Ewha Womans University

Three novel coordination polymers K-5[MnMo6Se8(CN)(6)] center dot A 8H(2)O (1), (Me4N)(4)[{Mn(H2O)(2)}(1.5)Mo6Se8(CN)(6)] center dot A 4H(2)O (2), and K-3[{Mn-2(H2O)(4)}Mo6Se8(CN)(6)] center dot A 7H(2)O (3) have been synthesized by layering of a methanol solution of [Mn(salen)]CH3COO (salen-N,N'-bis(salicylidene)ethylenediamine) on an aqueous solution of K-7[Mo6Se8(CN)(6)] center dot A 8H(2)O. The compounds have been characterized by single-crystal X-ray diffraction analysis. All structures are based on negatively charged porous polymer frameworks where CN groups of [Mo6Se8(CN)(6)](7-) cluster complexes are coordinated to Mn2+ cations. Cavities in the frameworks are filled by additional cations and solvate water molecules.

Brylev K.A. , Naumov N.G. , Virovets A.V. , Kim S-J. , Fedorov V.E.
Novel Three-Dimensional Coordination Polymers Based on [Mo6Se8(CN)6]7− Anions and Mn2+ Cations
Journal of Cluster Science. 2009. V.20. N1. P.165-176. DOI: 10.1007/s10876-008-0215-4 WOS OpenAlex

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