The First Octahedral Cluster Complexes With Terminal Formate Ligands: Synthesis, Structure, and Properties of K4[Re6S8(HCOO)6] and Cs4[Re6S8(HCOO)6] Научная публикация
Журнал |
Inorganic Chemistry
ISSN: 0020-1669 , E-ISSN: 1520-510X |
||||||||
---|---|---|---|---|---|---|---|---|---|
Вых. Данные | Год: 2009, Том: 48, Номер: 5, Страницы: 2309-2315 Страниц : 7 DOI: 10.1021/ic802178q | ||||||||
Авторы |
|
||||||||
Организации |
|
Реферат:
The hexarhenium anionic cluster complex with terminal formate ligands [Re6S8(HCOO)(6)](4-) was obtained by the room-temperature reaction between [Re6S8(HCOO)(6)](4-) and formic acid in an aqueous solution. The cluster was crystallized as a potassium or cesium salt and characterized by X-ray single-crystal diffraction and elemental analyses, IR, H-1 NMR, UV/vis, and luminescence spectroscopies. In particular, the emission quantum yield of the potassium salt of the Re-6 cluster anion in the solid phase was determined for the first time. The electronic structures of [Re6S8(HCOO)(6)](4-) and [Re6S8(HCOO)(6)](4-) were also elucidated by DFT calculations.
Библиографическая ссылка:
Brylev K.A.
, Mironov Y.V.
, Kozlova S.G.
, Fedorov V.E.
, Kim S-J.
, Pietzsch H-J.
, Stephan H.
, Ito A.
, Ishizaka S.
, Kitamura N.
The First Octahedral Cluster Complexes With Terminal Formate Ligands: Synthesis, Structure, and Properties of K4[Re6S8(HCOO)6] and Cs4[Re6S8(HCOO)6]
Inorganic Chemistry. 2009. V.48. N5. P.2309-2315. DOI: 10.1021/ic802178q WOS OpenAlex
The First Octahedral Cluster Complexes With Terminal Formate Ligands: Synthesis, Structure, and Properties of K4[Re6S8(HCOO)6] and Cs4[Re6S8(HCOO)6]
Inorganic Chemistry. 2009. V.48. N5. P.2309-2315. DOI: 10.1021/ic802178q WOS OpenAlex
Идентификаторы БД:
Web of science: | WOS:000263667700063 |
OpenAlex: | W2314064477 |