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The First Octahedral Cluster Complexes With Terminal Formate Ligands: Synthesis, Structure, and Properties of K4[Re6S8(HCOO)6] and Cs4[Re6S8(HCOO)6] Научная публикация

Журнал Inorganic Chemistry
ISSN: 0020-1669 , E-ISSN: 1520-510X
Вых. Данные Год: 2009, Том: 48, Номер: 5, Страницы: 2309-2315 Страниц : 7 DOI: 10.1021/ic802178q
Авторы Brylev Konstantin A. 1 , Mironov Yuri V. 1 , Kozlova Svetlana G. 1 , Fedorov Vladimir E. 1 , Kim Sung-Jin 2 , Pietzsch Hans-Jürgen 3 , Stephan Holger 3 , Ito Akitaka 4 , Ishizaka Shoji 4 , Kitamura Noboru 4
Организации
1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
2 Department of Chemistry and Nano Sciences, Ewha Womans University
3 Institut fur Radiopharmazie, Forschungszentrum Dresden-Rossendorf
4 Department of Chemistry, Graduate School of Science, Hokkaido University

Реферат: The hexarhenium anionic cluster complex with terminal formate ligands [Re6S8(HCOO)(6)](4-) was obtained by the room-temperature reaction between [Re6S8(HCOO)(6)](4-) and formic acid in an aqueous solution. The cluster was crystallized as a potassium or cesium salt and characterized by X-ray single-crystal diffraction and elemental analyses, IR, H-1 NMR, UV/vis, and luminescence spectroscopies. In particular, the emission quantum yield of the potassium salt of the Re-6 cluster anion in the solid phase was determined for the first time. The electronic structures of [Re6S8(HCOO)(6)](4-) and [Re6S8(HCOO)(6)](4-) were also elucidated by DFT calculations.
Библиографическая ссылка: Brylev K.A. , Mironov Y.V. , Kozlova S.G. , Fedorov V.E. , Kim S-J. , Pietzsch H-J. , Stephan H. , Ito A. , Ishizaka S. , Kitamura N.
The First Octahedral Cluster Complexes With Terminal Formate Ligands: Synthesis, Structure, and Properties of K4[Re6S8(HCOO)6] and Cs4[Re6S8(HCOO)6]
Inorganic Chemistry. 2009. V.48. N5. P.2309-2315. DOI: 10.1021/ic802178q WOS OpenAlex
Идентификаторы БД:
Web of science: WOS:000263667700063
OpenAlex: W2314064477
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Web of science 53
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