Abstract: The rhenium cyano-bridged cluster complex with a composition of beta-Ni(NH3)(5)}(2){Re6Te8(CN)(6)}]center dot 4H(2)O is obtained and structurally characterized. The compound crystallizes in the P (1) over bar triclinic space group with the unit cell parameters: a = 9.997(2) angstrom, b = 10.423(2) angstrom, c = 11.714(2) angstrom, alpha = 100.92(3)degrees, beta = 111.87(3)degrees, gamma = 98.05(3)degrees, V = 1082.1(4) angstrom(3), Z = 1, d(calc) = 4.072 g/cm(3). The rhenium atoms of the {Re6Te8} cluster core are coordinated by CN ligands to form the [Re6Te8(CN)(6)](4-) cluster; two nitrogen atoms of CN ligands trans-positioned with respect to each other are coordinated to Ni atoms in the {Ni(NH3)(5)}(2+) fragments to form the molecular complexes of [{Ni(NH3)(5)}(2){Re6Te8(CN)(6)}]. The crystal structure is the H-bonded packing of these molecular complexes and crystallization water molecules.

Cite: Brylev K.A. , Mironov Y.V. , Fedorov V.E.
Synthesis and crystal structure of the octahedral cyano-bridged cluster complex β-[{Ni(NH3)5}2{Re6Te8(CN)6}]·4H2O
Journal of Structural Chemistry. 2009. V.50. N6. P.1197-1200. DOI: 10.1007/s10947-009-0178-9 WOS OpenAlex

Original: Брылев К.А. , Миронов Ю.В. , Федоров В.Е.
Синтез и кристаллическая структура октаэдрического цианомостикового кластерного комплекса b-[{Ni(NH3)5}2{Re6Te8(CN)6}]·4H2O
Журнал структурной химии. 2009. Т.50. №6. С.1249-1252.

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Web of science:	WOS:000274300500029
OpenAlex:	W2007250527

Citing:

DB	Citing
OpenAlex	7
Web of science	4

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