Реферат: The salts Cs-4[Re6S8(OH)(6)]center dot 6H(2)O (1) and Cs-4[Re6Se8(OH)(6)]center dot 8H(2)O (2) were obtained by the reactions of Re6S8Br2 and Re6Se8Br2 with a CsOH melt with further solution of the products in water and crystallization of 1 and 2 from the aqueous solutions. The structure of the compounds was established by X-ray single crystal diffraction analysis. Compound 1 crystallizes in the orthorhombic space group Pbca with unit cell parameters a = 14.175(2) angstrom, b = 11.321(2) angstrom, c = 17.503(2) angstrom, V = 2808.5(7) angstrom(3), Z = 4, d(calc) = 5.003 g/cm(3); compound 2 crystallizes in the triclinic space group P (1) over bar with unit cell parameters a = 9.020(4) angstrom, b = 9.127(4) angstrom, c = 10.289(4) angstrom, alpha = 79.589(7)degrees, beta = 75.829(7)degrees, gamma = 72.186(7)degrees, V = 776.8(6) angstrom(3), Z = 1, d(calc) = 5.402 g/cm(3).

Библиографическая ссылка: Brylev K.A. , Mironov Y.V. , Kim S.-J. , Fedorov V.E.
Crystal structures of the octahedral rhenium cluster compexes Cs4[Re6S8(OH)6]·6H2O and Cs4[Re6Se8(OH)6]·8H2O
Journal of Structural Chemistry. 2007. V.48. N6. P.1118-1123. DOI: 10.1007/s10947-007-0179-5 WOS Scopus OpenAlex

Оригинальная: Брылев К.А. , Миронов Ю.В. , Ким С.-Д. , Федоров В.Е.
Кристаллические структуры октаэдрических кластерных комплексов рения Cs4[Re6S8(OH)6]∙6H2O и Cs4[Re6Se8(OH)6]∙8H2O
Журнал структурной химии. 2007. Т.48. №6. С.1183-1188.

Идентификаторы БД:

≡ Web of science:	WOS:000253573700019
≡ Scopus:	2-s2.0-39749193879
≡ OpenAlex:	W2001182366

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