A new cyanobridged one-dimensional coordination polymer based on the octahedral rhenium cluster [Re6Se8(CN)6]4−: Synthesis and crystal structure of [{Cu(H2O)0.5(en)2} {Cu(en)2}Re6Se8(CN)6]·3H2O Научная публикация
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Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766 |
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| Вых. Данные | Год: 2006, Том: 47, Номер: 4, Страницы: 771-776 Страниц : 6 DOI: 10.1007/s10947-006-0369-6 | ||
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Реферат:
The rhenium cluster complex [{Cu(H2O)(0.5)(en)(2)} {Cu(en)(2)}Re6Se8(CN)(6)]center dot 3H(2)O has been obtained by the reaction of an aqueous solution of K-4[Re6Se8(CN)(6)]center dot 3.5H(2)O with an aqueous solution of Cu(en)(2)Cl-2 using cross diffusion through a gel. The structure of the compound has been characterized by a single-crystal X-ray 3 diffraction method (a = 10.690(3) angstrom, b = 15.035(5) angstrom, c = 25.847(8) angstrom, V= 4154(2) angstrom(3), Z = 4, space group P2(1)2(1)2(1), R = 0.0651). Cluster anions [Re6Se8(CN)(6)](4-) in the complex are connected with Cu2+ cations by cyano bridges resulting in zigzag chains. Coordination environment of cations is completed by ethylenediamine molecules. Additionally each cluster anion is coordinated by one terminal fragment {Cu(H2O)(0.5)(en)(2)}.
Библиографическая ссылка:
Naumov N.G.
, Mironov Y.V.
, Brylev K.A.
, Fedorov V.E.
A new cyanobridged one-dimensional coordination polymer based on the octahedral rhenium cluster [Re6Se8(CN)6]4−: Synthesis and crystal structure of [{Cu(H2O)0.5(en)2} {Cu(en)2}Re6Se8(CN)6]·3H2O
Journal of Structural Chemistry. 2006. V.47. N4. P.771-776. DOI: 10.1007/s10947-006-0369-6 WOS OpenAlex
A new cyanobridged one-dimensional coordination polymer based on the octahedral rhenium cluster [Re6Se8(CN)6]4−: Synthesis and crystal structure of [{Cu(H2O)0.5(en)2} {Cu(en)2}Re6Se8(CN)6]·3H2O
Journal of Structural Chemistry. 2006. V.47. N4. P.771-776. DOI: 10.1007/s10947-006-0369-6 WOS OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000243492300026 |
| OpenAlex: | W2316141310 |