Synthesis and Structure of Antimony Complex Compounds [(4-N,N-Me 2 C 6 H 4 ) 3 MeSb]I and [(4-N,N-Me 2 C 6 H 4 ) 3 MeSb] 2 [Hg 2 I 6 ]·2DMSO

Synthesis and Structure of Antimony Complex Compounds [(4-N,N-Me 2 C 6 H 4 ) 3 MeSb]I and [(4-N,N-Me 2 C 6 H 4 ) 3 MeSb] 2 [Hg 2 I 6 ]·2DMSO Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2021, Volume: 91, Number: 7, Pages: 1361-1367 Pages count : 7 DOI: 10.1134/S1070363221070148

Authors

Egorova I.V. ¹ , Zhidkov V.V. ¹ , Grinishak I.P. ¹ , Rodionova N.A. ¹ , Bagryanskaya I.Yu. ² , Pervukhina N.V. ³

Affiliations

1	Blagoveschensk State Pedagogical University
2	N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry
3	A.V. Nikolaev Institute of Inorganic Chemistry

It was first found that the alkylation of tris(4-N,N-dimethylaminophenyl)stibine with methyliodide leads to the formation of tris(4-N,N-dimethylaminophenyl)methylstibonium iodide which decomposes in hot water to tris(4-N,N-dimethylaminophenyl)stibine. The reaction of [(4-N,N-Me 2 C 6 H 4 ) 3 MeSb]I with HgI 2 in DMSO yields [(4-N,N-(Me) 2 C 6 H 4 ) 3 MeSb] 2 [Hg 2 I 6 ]·2DMSO, in which a significant distortion of the tetrahedral cation coordination is caused by the additional interaction of the oxygen atom of the DMSO molecule with the antimony atom.

Egorova I.V. , Zhidkov V.V. , Grinishak I.P. , Rodionova N.A. , Bagryanskaya I.Y. , Pervukhina N.V.
Synthesis and Structure of Antimony Complex Compounds [(4-N,N-Me 2 C 6 H 4 ) 3 MeSb]I and [(4-N,N-Me 2 C 6 H 4 ) 3 MeSb] 2 [Hg 2 I 6 ]·2DMSO
Russian Journal of General Chemistry. 2021. V.91. N7. P.1361-1367. DOI: 10.1134/S1070363221070148 WOS OpenAlex

Егорова И.В. , Жидков В.В. , Гринишак И.П. , Родионова Н.А. , Багрянская И.Ю. , Первухина Н.В.
Синтез и строение комплексных соединений сурьмы [(4-N,N-Me2C6 H4)3MeSb]I и [(4-N,N-Me2C6H4)3MeSb]2[Hg2I6]•2DMSO
Журнал общей химии. 2021. Т.91. №7. С.1100-1107. DOI: 10.31857/S0044460X21070143 OpenAlex

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