On the Reaction of Gold(III) Complexes with Methionine Full article
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Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613 |
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| Output data | Year: 2024, DOI: 10.1134/S0036023624602253 | ||
| Tags | gold(III) compounds, redox processes, methionine, glutathione | ||
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Abstract:
The reactions of gold(III) complexes AuCl4−, Au(bipy)Cl , Au(en) , and Au(C9H19N4)2+ with methionine (HMet) were studied in aqueous solutions (pH 2.0 and 7.4; I = 0.2 M (NaCl), CAu = (5–10) × 10–5 mol/L, CHMet < (6–50) × 10–5 mol/L) at 25°C. Methionine reduces gold(III) to gold(I), but the reactions proceed much more slowly (by hundreds of times) than under the action of thiols. The rate of reactions with HMet markedly decreases with increasing denticity of ligands in the gold(III) complex.
Cite:
Kharlamova V.Y.
, Mironov I.V.
On the Reaction of Gold(III) Complexes with Methionine
Russian Journal of Inorganic Chemistry. 2024. DOI: 10.1134/S0036023624602253
On the Reaction of Gold(III) Complexes with Methionine
Russian Journal of Inorganic Chemistry. 2024. DOI: 10.1134/S0036023624602253
Original:
Харламова В.Ю.
, Миронов И.В.
О ВЗАИМОДЕЙСТВИИ КОМПЛЕКСОВ ЗОЛОТА(III) С МЕТИОНИНОМ
Журнал неорганической химии. 2024. Т.69. №10. С.1459–1465. DOI: 10.31857/S0044457X24100125
О ВЗАИМОДЕЙСТВИИ КОМПЛЕКСОВ ЗОЛОТА(III) С МЕТИОНИНОМ
Журнал неорганической химии. 2024. Т.69. №10. С.1459–1465. DOI: 10.31857/S0044457X24100125
Dates:
| Submitted: | Jun 8, 2024 |
| Accepted: | Jun 27, 2024 |
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