Cyanide-Bridged Bimetallic High Spin Molecules

Cyanide-Bridged Bimetallic High Spin Molecules Full article

Journal

Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals (CD-ROM)
ISSN: 1058-725X , E-ISSN: 1026-5422

Output data

Year: 1999, Volume: 335, Number: 1, Pages: 483-494 Pages count : 12 DOI: 10.1080/10587259908028890

Tags

metallocyanide, cyanide-bridged, iron(III), manganese(III), chromium(III), magnetism

Authors

Marvilliers Arnaud ¹ , Mallah Talal ¹ , Riviere Eric ¹ , Parsons Simon ² , Munoz Carmen ³ , Vostrikova Kira E. ⁴

Affiliations

1	Université Paris Sud, Laboratoire de Chimie Inorganique, URA CNRS 420, 91405 , Orsay, France
2	University of Edinburgh, Department of Chemistry , West Main Road, EM9 1PM , Edinburgh , UK
3	Departamento de Fisica Aplicada, Universidad Politècnica de Valencia, 46071, Vàlencia, Spain
4	Inorganic Chemistry Institute , Lavrentieva Av., 630090 , Novosibirsk , Russia

The synthesis, characterisation and magnetic properties of two series of polynuclear cyanide-bridged high spin molecules are presented. Tetranuclear compounds of general formula (NC)3M(CNM′L5)3 7H2O (M = FeIII, CrIII and M′ = MnIII, FeIII) are obtained by using peripheral complexes with pentadentate ligands. Pentanuclear complexes ((NC)3Cr[CNNi(ligand)2NC]3Cr(CN)3 6H2O) are designed owing to steric hindrance induced by bulky bidentate ligands chelating the peripheral NiII complexes. The magnetic properties show that ground states with spin up to 9 may be obtained. https://www.webofscience.com/wos/woscc/full-record/WOS:000083449600046

Marvilliers A. , Mallah T. , Riviere E. , Parsons S. , Munoz C. , Vostrikova K.E.
Cyanide-Bridged Bimetallic High Spin Molecules
Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals (CD-ROM). 1999. V.335. N1. P.483-494. DOI: 10.1080/10587259908028890 WOS OpenAlex

Published online:

Sep 12, 1998

Web of science:	WOS:000083449600046
OpenAlex:	W1992400745

DB	Citing
OpenAlex	6
Web of science	5