Cyanide-Bridged Bimetallic High Spin Molecules Full article
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Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals (CD-ROM)
ISSN: 1058-725X , E-ISSN: 1026-5422 |
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Output data | Year: 1999, Volume: 335, Number: 1, Pages: 483-494 Pages count : 12 DOI: 10.1080/10587259908028890 | ||||||||
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Abstract:
The synthesis, characterisation and magnetic properties of two series of polynuclear cyanide-bridged high spin molecules are presented. Tetranuclear compounds of general formula (NC)3M(CNM′L5)3 7H2O (M = FeIII, CrIII and M′ = MnIII, FeIII) are obtained by using peripheral complexes with pentadentate ligands. Pentanuclear complexes ((NC)3Cr[CNNi(ligand)2NC]3Cr(CN)3 6H2O) are designed owing to steric hindrance induced by bulky bidentate ligands chelating the peripheral NiII complexes. The magnetic properties show that ground states with spin up to 9 may be obtained.
Cite:
Marvilliers A.
, Mallah T.
, Riviere E.
, Parsons S.
, Munoz C.
, Vostrikova K.E.
Cyanide-Bridged Bimetallic High Spin Molecules
Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals (CD-ROM). 1999. V.335. N1. P.483-494. DOI: 10.1080/10587259908028890 OpenAlex
Cyanide-Bridged Bimetallic High Spin Molecules
Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals (CD-ROM). 1999. V.335. N1. P.483-494. DOI: 10.1080/10587259908028890 OpenAlex
Identifiers:
OpenAlex: | W1992400745 |
Citing:
DB | Citing |
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OpenAlex | 6 |