1D Polymeric Iodoantimonates(III) with 1-Methylpyridinium and 3-Bromo-1-methylpyridinium Cations: Structures and Properties

1D Polymeric Iodoantimonates(III) with 1-Methylpyridinium and 3-Bromo-1-methylpyridinium Cations: Structures and Properties Full article

Journal

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Output data

Year: 2024, Volume: 50, Number: 10, Pages: 809-816 Pages count : 8 DOI: 10.1134/s1070328424600700

Authors

Shentseva I.A. ¹ , Usol’tsev A.N. ¹ , Korobeinikov N.A. ^1,2 , Adonin S.A. ^1,3

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia
3	Favorskii Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia

The reactions of SbI3 with iodides of cations of the pyridinium family in a mixture of acetonitrile and acetone afford two polymeric iodoantimonate complexes: (1-MePy){[SbI4]} (I) and (3-Br-1-MePy){[SbI4]} (II). Specific features of the crystal structures are determined by X-ray diffraction (XRD). The thermal stability of compounds I and II is evaluated by thermogravimetry. The optical forbidden bandgaps are estimated from the diffuse reflectance spectra.

Shentseva I.A. , Usol’tsev A.N. , Korobeinikov N.A. , Adonin S.A.
1D Polymeric Iodoantimonates(III) with 1-Methylpyridinium and 3-Bromo-1-methylpyridinium Cations: Structures and Properties
Russian Journal of Coordination Chemistry. 2024. V.50. N10. P.809-816. DOI: 10.1134/s1070328424600700 WOS Scopus РИНЦ OpenAlex

Шенцева И.А. , Усольцев А.Н. , Коробейников Н.А. , Адонин С.А.
Одномерные полимерные иодантимонаты(III) с катионами 1-метилпиридиния и 3-бром-1-метилпиридиния: структура и свойства
Координационная химия. 2024. С.1.

Submitted:	May 15, 2024
Accepted:	Jun 5, 2024
Published print:	Nov 29, 2024

Web of science:	WOS:001372682700011
Scopus:	2-s2.0-85211316023
Elibrary:	75182954
OpenAlex:	W4405149573

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