Synthesis and Structure of Ag(I) Complexes with Tris(3,5-Dimethylpyrazol-1-yl)Methane and β-Diketones

Synthesis and Structure of Ag(I) Complexes with Tris(3,5-Dimethylpyrazol-1-yl)Methane and β-Diketones Full article

Journal

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Output data

Year: 2024, Volume: 65, Pages: 2327–2344 Pages count : DOI: 10.1134/S0022476624110180

Authors

Vikulova E.S. ¹ , Sukhikh T.S. ¹ , Barysheva A.C. ^1,2 , Varvarinskaya S.E. ³ , Ilyin I.Y. ¹ , Shakirova O.G. ⁴ , Morozova N.B. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Novosibirsk State Technical University, Novosibirsk, Russia
3	Novosibirsk State University, Novosibirsk, Russia
4	Komsomolsk-na-Amure State University, Komsomolsk-on-Amur, Russia

The possibility of forming molecular Ag(I) complexes with tris(3,5-dimethylpyrazol-1-yl)methane (HC(3,5-Me2pz)3) and fluorinated β-diketones (hexafluoroacetylacetone (Hhfac) and trifluoroacetylacetone (Htfac)) is tested to expand the library of potential precursors for the chemical vapor deposition of Ag containing materials. It is established that the interaction of HC(3,5-Me2pz)3 with silver β-diketonates leads to the formation of [Ag{HC(3,5-Me2pz)3}2]+ cationic complexes. At the same time, a stable desired product [Ag{HC(3,5-Me2pz)3}hfac] (L = hfac) was isolated and characterized. The structures of [Ag{HC(3,5-Me2pz)3}2](tfac) and as series of solvates [Ag{HC(3,5-Me2pz)3}(hfac)]·½THF and [Ag{HC(3,5-Me2pz)3}2](L)Solvx (L = hfac, Solv = Et2O (x = ¼), C7H8 (x = ½), CHCl3 (x = 1); L = tfac, Solv = THF (x = 1)) are determined by XRD. Structures of the cationic and molecular complexes are compared with those of related compounds.

Vikulova E.S. , Sukhikh T.S. , Barysheva A.C. , Varvarinskaya S.E. , Ilyin I.Y. , Shakirova O.G. , Morozova N.B.
Synthesis and Structure of Ag(I) Complexes with Tris(3,5-Dimethylpyrazol-1-yl)Methane and β-Diketones
Journal of Structural Chemistry. 2024. V.65. P.2327–2344. DOI: 10.1134/S0022476624110180 WOS Scopus РИНЦ OpenAlex

Викулова Е.С. , Сухих Т.С. , Барышева А.C. , Варваринская С.Е. , Ильин И.Ю. , Шакирова О.Г. , Морозова Н.Б.
Синтез и строение комплексов Ag(I) с трис(3,5-диметилпиразол-1-ил)метаном и β-дикетонами
Журнал структурной химии. 2024. Т.65. №11. 136279 :1-19. DOI: 10.26902/JSC_id136279 РИНЦ OpenAlex

Published print:

Dec 2, 2024

Web of science:	WOS:001376818100001
Scopus:	2-s2.0-85211159362
Elibrary:	75143238
OpenAlex:	W4404905122

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