Potassium and Rubidium Benzoyltrifluoroacetonates: A Crystal Chemical Study and Thermal Properties

Potassium and Rubidium Benzoyltrifluoroacetonates: A Crystal Chemical Study and Thermal Properties Научная публикация

Журнал

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Вых. Данные

Год: 2020, Том: 61, Страницы: 439–448 Страниц : DOI: 10.1134/S0022476620030105

Ключевые слова

potassium, rubidium, benzoyltrifluoroacetone, X-ray crystallography, thermal analysis

Авторы

Kochelakov D.V. ^1,2 , Vikulova E.S. ¹ , Kuratieva N.V. ^1,2

Организации

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia

Complexes of potassium and rubidium with benzoyltrifluoroacetone (C6H5COCH2COCF3 = Hbtfac) of the composition M(btfac)(H2O)x, where M = K, Rb, x ∈ [0.5 … 1] are synthesized for the first time. The compounds are characterized by the elemental analysis and IR spectroscopy. By X-ray crystallography the crystal structures of M(btfac)(H2O) are determined: for the potassium complex a = 10.4955(4) Å, b = 13.9715(6) Å, c = 7.5197(3) Å, α = β = γ = 90°, space group Pcc2, Z = 4, R = 0.0242 [I > 2σ(I)]; for the rubidium complex a = 10.6363(8) Å, b = 27.9354(18) Å, c = 7.7205(5) Å, α = 90°, β = 93.759(2)°, γ = 90°, space group P21/c, Z = 4, R = 0.0287. The compounds represent layered coordination polymers where the metal cation coordinates eight oxygen atoms of four β-diketonate anions or four fluorine atoms of four β-diketonate ligands and four oxygen atoms of water molecules. The structures of M(btfac)(H2O) complexes with M = K, Rb, Cs are compared and the common structural motifs are revealed. From the thermogravimetry data the melting points and temperature ranges of the stability of anhydrous complexes are found.

Kochelakov D.V. , Vikulova E.S. , Kuratieva N.V.
Potassium and Rubidium Benzoyltrifluoroacetonates: A Crystal Chemical Study and Thermal Properties
Journal of Structural Chemistry. 2020. V.61. P.439–448. DOI: 10.1134/S0022476620030105 Scopus OpenAlex

Кочелаков Д.В. , Викулова Е.С. , Куратьева Н.В.
Бензоилтрифторацетонаты калия и рубидия: кристаллохимическое исследование и термические свойства
Журнал структурной химии. 2020. Т.61. №3. С.462. DOI: 10.26902/JSC_id52876 OpenAlex

Scopus:	2-s2.0-85088638997
OpenAlex:	W3046140055

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