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The Tripodal Ligand’s 4f Complexes: Use in Molecular Magnetism Научная публикация

Журнал Inorganics
ISSN: 2304-6740
Вых. Данные Год: 2023, Том: 11, Номер: 7, Номер статьи : 307, Страниц : 29 DOI: 10.3390/inorganics11070307
Ключевые слова tripodal ligands; lanthanides; single-molecule magnets; single-ion magnets; axiality
Авторы Vostrikova Kira E. 1
Организации
1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090 Novosibirsk, Russia

Информация о финансировании (2)

1 Министерство науки и высшего образования Российской Федерации 121031700313-8
2 Российский научный фонд 23-23-00437

Реферат: A predictable type of coordination is a key property of tripodal ligands. Homo- and heteroleptic lanthanide complexes with tripodal ligands are a representative class of compounds. However, despite the fact that many of them are paramagnetic, their magnetic behavior is poorly studied. This is because their photophysical and catalytic properties are considered more attractive. In the present review, we try to summarize the available structural information and only a few examples of data on magnetic properties in order to draw some conclusions about the prospect of such ligands in the design of quantum molecular magnets involving lanthanide (Ln) ions. We would also like to catch the reader’s attention to the fact that, despite the consideration of a large part of the currently known Ln compounds with tripodal ligands, this review is not exhaustive. However, our goal is to draw the attention of magnetochemists and theoreticians to a whole niche of air-stable Ln complexes that is still out of their field of vision.
Библиографическая ссылка: Vostrikova K.E.
The Tripodal Ligand’s 4f Complexes: Use in Molecular Magnetism
Inorganics. 2023. V.11. N7. 307 :1-29. DOI: 10.3390/inorganics11070307 WOS Scopus OpenAlex
Даты:
Поступила в редакцию: 12 июн. 2023 г.
Опубликована в печати: 20 июл. 2023 г.
Идентификаторы БД:
Web of science: WOS:001036228400001
Scopus: 2-s2.0-85175114470
OpenAlex: W4385067830
Цитирование в БД:
БД Цитирований
OpenAlex 7
Web of science 6
Scopus 2
Альметрики: