Intramolecular Dynamics of Lanthanide(III) Tetraoxadiaza Macrocycle Complexes in Solution as Studied by NMR.

Intramolecular Dynamics of Lanthanide(III) Tetraoxadiaza Macrocycle Complexes in Solution as Studied by NMR. Full article

Journal

Journal of Inclusion Phenomena and Macrocyclic Chemistry
ISSN: 2212-1765 , E-ISSN: 0923-0750

Output data

Year: 2002, Volume: 43, Number: 1/2, Pages: 25-29 Pages count : 5 DOI: 10.1023/a:1020492027829

Authors

Babailov S.P. ¹ , Nikulina L.D. ¹ , Krieger J.H. ¹

Affiliations

1	Radiospectroscopic Laboratory, Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russia

1H and 13C NMR and 1H NMR relaxation spectroscopy (RS)measurements are reported for the CDCl3 and CD2Cl2 solutions of [La(NO3)3(diaza-18-crown-6)] ({bf I}), [Pr(NO3)3(diaza-18-crown-6)] ({bf II}) and [Nd(NO3)3(diaza-18-crown-6)] ({bf III}) complexes. Temperature dependencies of the 1H NMR spectra of II have been analyzed using the dynamic NMR methods for multi-site exchange. Enantiomeric isomer interconversion in II is characterized by H = 21.5 4 kJ mol-1. Studies of the values of the lanthanide-induced shifts and the longitudinal relaxation rate enhancement revealed that the structure of complexes in solution is similar to that reported for the [La(NO3)3(18-crown-6)] complex in the crystal state. Nevertheless, it appears that the principal values of the molar paramagnetic susceptibility tensor (i) significantly differ in complexes II and III. The possible reasons for the different characteristics of these complexes are discussed.

Babailov S.P. , Nikulina L.D. , Krieger J.H.
Intramolecular Dynamics of Lanthanide(III) Tetraoxadiaza Macrocycle Complexes in Solution as Studied by NMR.
Journal of Inclusion Phenomena and Macrocyclic Chemistry. 2002. V.43. N1/2. P.25-29. DOI: 10.1023/a:1020492027829 OpenAlex

Published print:

Jun 1, 2002

OpenAlex:

W327237608

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