Time dependence of the NMR line shape for systems with chemical exchange in a zero saturation limit

Time dependence of the NMR line shape for systems with chemical exchange in a zero saturation limit Full article

Journal

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Output data

Year: 2006, Volume: 47, Number: 3, Pages: 442-446 Pages count : 5 DOI: 10.1007/s10947-006-0320-x

Authors

Babailov S.P. ¹ , Mainichev D.A. ¹

Affiliations

1	A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Russia

An expression has been derived for the time dependence of the NMR line shape for systems with many-site chemical exchange in the absence of spin-spin coupling, in a zero saturation limit. The dynamics of variation of the NMR line shape with time is considered in detail for the case of two-site chemical exchange. Mathematica programs have been designed for numerical simulation of the NMR spectra of chemical exchange systems. The analytical expressions obtained are useful for NMR line shape simulations for systems with photoinduced chemical exchange.

Babailov S.P. , Mainichev D.A.
Time dependence of the NMR line shape for systems with chemical exchange in a zero saturation limit
Journal of Structural Chemistry. 2006. V.47. N3. P.442-446. DOI: 10.1007/s10947-006-0320-x WOS Scopus OpenAlex

Published print:

Oct 1, 2006

Web of science:	WOS:000242330700007
Scopus:	2-s2.0-33750729255
OpenAlex:	W2094990872

DB	Citing
Scopus	1
OpenAlex	1
Web of science	3