The First Homoleptic Complex of Seven-Coordinated Osmium: Synthesis and Crystallographical Evidence of Pentagonal Bipyramidal Polyhedron of Heptacyanoosmate(IV)

The First Homoleptic Complex of Seven-Coordinated Osmium: Synthesis and Crystallographical Evidence of Pentagonal Bipyramidal Polyhedron of Heptacyanoosmate(IV) Full article

Journal

Crystals
ISSN: 2073-4352

Output data

Year: 2016, Volume: 6, Number: 9, Article number : 102, Pages count : 9 DOI: 10.3390/cryst6090102

Authors

Peresypkina Eugenia ^1,2 , Gavriluta Anatolie ³ , Vostrikova Kira E. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk 630090, Russia
2	Novosibirsk State University, Novosibirsk 630090, Russia
3	Laboratoire des Multimatériaux et Interfaces (UMR 5615), Université Claude Bernard Lyon 1, 69622 Villeurbanne Cedex, France

The ligand exchange in (n-Bu4N)2OsIVCl6 (n-Bu4N = tetra-n-butylammonium) leads to the formation of the osmium(IV) heptacyanide, the first fully inorganic homoleptic complex of heptacoordinated osmium. The single-crystal X-ray diffraction (SC-XRD) study reveals the pentagonal bipyramidal molecular structure of the [Os(CN)7]3− anion. The latter being a diamagnetic analogue of the highly anisotropic paramagnetic synthon, [ReIV(CN)7]3− can be used for the synthesis of the model heterometallic coordination compounds for the detailed study and simulation of the magnetic properties of the low-dimensional molecular nanomagnets involving 5d metal heptacyanides. Keywords: osmium; heptacyanoosmate(IV); pentagonal bipyramid polyhedron

Peresypkina E. , Gavriluta A. , Vostrikova K.E.
The First Homoleptic Complex of Seven-Coordinated Osmium: Synthesis and Crystallographical Evidence of Pentagonal Bipyramidal Polyhedron of Heptacyanoosmate(IV)
Crystals. 2016. V.6. N9. 102 :1-9. DOI: 10.3390/cryst6090102 Scopus OpenAlex

Scopus:	2-s2.0-84984791953
OpenAlex:	W2511436184

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Scopus	4
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