A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid

A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid Full article

Journal

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Output data

Year: 2019, Volume: 60, Number: 2, Pages: 279-283 Pages count : 5 DOI: 10.1134/s0022476619020136

Tags

copper(II) complexes, crystal structure, coordination polymers, chiral complexes, malic acid

Authors

Zavakhina M.S. ^1,2 , Samsonenko D.G. ^1,2 , Fedin V.P. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Novosibirsk State University, Russia

The [Cu8(S-mal)4(bptc)(H2O)12] · 0.5H4bptc · 7.5H2O coordination polymer is obtained by heating the copper(II) nitrate, S-malic acid (H3mal), and biphenyl-3,3′,5,5′-tetracarboxylic (H4bptc) acid solution in the water-N,N-diethylformamide mixture. The crystal structure is determined from XRD data. The compound has a three-dimensional homochiral framework with channels filled by crystallization molecules of tetracarboxylic acid and water. The composition and structure of the coordination polymer obtained are confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

Zavakhina M.S. , Samsonenko D.G. , Fedin V.P.
A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid
Journal of Structural Chemistry. 2019. V.60. N2. P.279-283. DOI: 10.1134/s0022476619020136 WOS Scopus OpenAlex

Завахина М.С. , Самсоненко Д.Г. , Федин В.П.
Гомохиральный координационный полимер на основе меди(II), S-яблочной и бифенил-3,3',5,5'-тетракарбоновой кислот
Журнал структурной химии. 2019. Т.60. №2. С.290-295. DOI: 10.26902/jsc_id39227 OpenAlex

Submitted:	Sep 12, 2018
Accepted:	Oct 1, 2018
Published online:	May 6, 2019

Web of science:	WOS:000467128100013
Scopus:	2-s2.0-85065438454
OpenAlex:	W2944605610

DB	Citing
Scopus	8
OpenAlex	8
Web of science	8