Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units

Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units Full article

Journal

CrystEngComm
ISSN: 1466-8033

Output data

Year: 2019, Volume: 21, Number: 15, Pages: 2524-2533 Pages count : 10 DOI: 10.1039/c9ce00073a

Authors

Cheplakova Anastasia M. ^1,2 , Kovalenko Konstantin A. ^1,2 , Samsonenko Denis G. ^1,2 , Vinogradov Andrey S. ³ , Karpov Victor M. ³ , Platonov Vyacheslav E. ³ , Fedin Vladimir P. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Akad. Lavrentiev Av., Novosibirsk, Russian Federation
2	Novosibirsk State University
3	N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, SB RAS, 9 Akad. Lavrentiev Av., Novosibirsk, Russian Federation

We present a series of six novel Zn(II) complexes containing anions of perfluorinated biphenyl-4,4′-dicarboxylate (oFBPDC2−). Among them are the 0D complex [Zn(eg)3](oFBPDC) (eg = ethylene glycol), the 1D [Zn(H2O)(ur)(oFBPDC)] (ur = urotropine) and [Zn(CH3OH)2(CH3OCH2CH2OH)(oFBPDC)] and the 2D layered [Zn2(CH3CN)2(oFBPDC)2]·2C6H6·2CH3CN, [Zn2(H2O)2(oFBPDC)2]·4(CH3)2CO, [{Zn4(μ3-OCH3)4}(CH3OH)4(oFBPDC)2]·[{Zn4(μ3-OCH3)4}(H2O)(CH3OH)3(oFBPDC)2]·13CH3OH. The latter coordination polymer is built up by unique Zn4(OCH3)4 cuboidal units. The complexes are characterized by single-crystal X-ray diffraction, FT-IR, elemental analysis, and TGA. Investigation of the CO2 adsorption at 195 K on [Zn2(CH3CN)2(oFBPDC)2] and [Zn2(H2O)2(oFBPDC)2] of the layered polymeric structure revealed that they have BET surface areas of 334.8 and 150.6 m2 g−1, respectively.

Cheplakova A.M. , Kovalenko K.A. , Samsonenko D.G. , Vinogradov A.S. , Karpov V.M. , Platonov V.E. , Fedin V.P.
Structural diversity of zinc(ii) coordination polymers with octafluorobiphenyl-4,4′-dicarboxylate based on mononuclear, paddle wheel and cuboidal units
CrystEngComm. 2019. V.21. N15. P.2524-2533. DOI: 10.1039/c9ce00073a Scopus OpenAlex

Scopus:	2-s2.0-85064081008
OpenAlex:	W2916780661

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