Synthesis and Crystal Structure of Coordination Polymer [Sc2(HOCH2CH2OH)4(tFBDC)3] · 2HOCH2CH2OH

Synthesis and Crystal Structure of Coordination Polymer [Sc2(HOCH2CH2OH)4(tFBDC)3] · 2HOCH2CH2OH Full article

Journal

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Output data

Year: 2019, Volume: 60, Number: 2, Pages: 289-293 Pages count : 5 DOI: 10.1134/s002247661902015x

Authors

Cheplakova A.M. ^1,2 , Samsonenko D.G. ^1,2 , Fedin V.P. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia

The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in ethylene glycol leads to the formation of the complex [Sc2(HOCH2CH2OH)4(tFBDC)3]·2HOCH2CH2OH (tFBDC2− = tetrafluoroterephthalate) (1). According to the X-ray data, compound 1 is a chain coordination polymer. Sc(III) cations and tFBDC2− anions form double chains (ribbons). The coordination number of Sc(III) is completed to seven by ethylene glycol molecules acting as chelate ligands. There is a complex system of hydrogen bonding interactions induced by oxygen atoms of carboxylic groups of perfluorinated ligands and coordinated and lattice ethylene glycol.

Cheplakova A.M. , Samsonenko D.G. , Fedin V.P.
Synthesis and Crystal Structure of Coordination Polymer [Sc2(HOCH2CH2OH)4(tFBDC)3] · 2HOCH2CH2OH
Journal of Structural Chemistry. 2019. V.60. N2. P.289-293. DOI: 10.1134/s002247661902015x Scopus OpenAlex

Чеплакова А.М. , Самсоненко Д.Г. , Федин В.П.
Синтез и кристаллическая структура металл-органического координационного полимера [Sc2(HOCH2CH2OH)4(tFBDC)3]·2HOCH2CH2OH
Журнал структурной химии. 2019. Т.60. №2. С.301-305. DOI: 10.26902/jsc_id39229 OpenAlex

Scopus:	2-s2.0-85065411168
OpenAlex:	W2943862136

DB	Citing
Scopus	5
OpenAlex	4