Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]

Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3] Full article

Journal

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Output data

Year: 2018, Volume: 59, Number: 2, Pages: 494-496 Pages count : 3 DOI: 10.1134/s0022476618020348

Authors

Cheplakova A.M. ^1,2 , Fedoseev I.S. ² , Dorovatovskii P.V. ³ , Lazarenko V.A. ³ , Zubavichus Ya.V. ³ , Khrustalev V.N. ⁴ , Fedin V.P. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia
3	National Research Center "Kurchatov Institute", Moscow, Russia
4	Peoples' Friendship University of Russia, Moscow, Russia

The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in methanol is accompanied by acid decarboxylation and the formation of a tris-(2,3,5,6- tetrafluorobenzoato)scandium complex compound. According to the data of the single crystal X-ray diffraction analysis, the compound has a chain structure due to the carboxylate anion functioning as a μ2-bridging ligand. The polymer chains are linked together by π–π interactions between the phenyl rings.

Cheplakova A.M. , Fedoseev I.S. , Dorovatovskii P.V. , Lazarenko V.A. , Zubavichus Y.V. , Khrustalev V.N. , Fedin V.P.
Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]
Journal of Structural Chemistry. 2018. V.59. N2. P.494-496. DOI: 10.1134/s0022476618020348 Scopus OpenAlex

Scopus:	2-s2.0-85048144014
OpenAlex:	W2794752317

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