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Rhenium octahedral clusters in mesoporous MIL-101: luminescence and sorption properties Full article

Journal Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285
Output data Year: 2014, Volume: 63, Number: 7, Pages: 1487-1492 Pages count : 6 DOI: 10.1007/s11172-014-0624-5
Authors Cheplakova A.M. 1 , Kovalenko K.A. 1,2 , Shestopalov M.A. 1,2 , Brylev K.A. 1,2 , Fedin V.P. 1,2
Affiliations
1 Novosibirsk National Research State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation
2 A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

Abstract: Rhenium octahedral cluster complexes were immobilized into the cages mesoporous chromium(III) terephthalate MIL-101 in two ways: by the inclusion of anionic clusters as guests and by the coordination of cluster complexes through ditopic organic ligands (4,4′-bipyridyl) to metal atoms of the framework. The influence of the cluster complex—metal-organic matrix type of bonding on luminescence and sorption properties was studied. It was shown that the intensity of luminescence of the hybrid compound in which the cluster complexes are coordinated through ditopic organic ligands is considerably lower than that of the inclusion compound of cluster complexes in the coordination polymer cages.
Cite: Cheplakova A.M. , Kovalenko K.A. , Shestopalov M.A. , Brylev K.A. , Fedin V.P.
Rhenium octahedral clusters in mesoporous MIL-101: luminescence and sorption properties
Russian Chemical Bulletin. 2014. V.63. N7. P.1487-1492. DOI: 10.1007/s11172-014-0624-5 WOS Scopus OpenAlex
Original: Чеплакова А.М. , Коваленко К.А. , Шестопалов М.А. , Брылев К.А. , Федин В.П.
Октаэдрические кластеры рения в мезопористом MIL-101: люминесцентные и сорбционные свойства
Известия Академии наук. Серия химическая. 2014. Т.63. №7. С.1487 - 1492.
Identifiers:
Web of science: WOS:000350878300004
Scopus: 2-s2.0-84924242755
OpenAlex: W2018871566
Citing:
DB Citing
Scopus 7
OpenAlex 8
Web of science 7
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