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Vapor pressure of tetrasubstituted metal phthalocyanines bearing fluorine substituents in non-peripheral positions Full article

Journal Journal of Porphyrins and Phthalocyanines
ISSN: 1099-1409 , E-ISSN: 1088-4246
Output data Year: 2024, Volume: 28, Pages: 618-625 Pages count : 8 DOI: 10.1142/s1088424624500330
Tags fluorosubstituted phthalocyanine, vapor pressure, sublimation enthalpy, intermolecular interactions
Authors Bonegardt Dmitry V. 1 , Trubin Sergei V. 1 , Sukhikh Aleksandr S. 1 , Klyamer Darya D. 1 , Basova Tamara V. 1
Affiliations
1 Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Lavrentiev Pr., Novosibirsk, 630090, Russia

Abstract: In this paper, the temperature dependence of the saturated vapor pressure of fluorosubstituted phthalocyanines with substituents in non-peripheral positions of the macroring, viz. MPcF4-np, M=Cu, Fe, Co, VO, was investigated by the Knudsen effusion method with mass spectrometric registration of the gaseous phase composition. The standard thermodynamic parameters ΔH°T and ΔS°T of the sublimation process of these compounds were determined. The results were compared with the vapor pressure of the corresponding MPcF4-p analogs bearing F-substituents in the peripheral positions. It was shown that the volatility decreased in the order of VOPcF4-np>CoPcF4-np ~ CuPcF4-np ~ FePcF4-np>ZnPcF4-np, which correlated with the increase in their crystal lattice energy in the same order. The volatility of most MPcF4-np (M=Cu, Zn, Co, VO) was lower than that of MPcF4-p. The results were analyzed from the point of view of crystal packing and intermolecular interactions in the crystal.
Cite: Bonegardt D.V. , Trubin S.V. , Sukhikh A.S. , Klyamer D.D. , Basova T.V.
Vapor pressure of tetrasubstituted metal phthalocyanines bearing fluorine substituents in non-peripheral positions
Journal of Porphyrins and Phthalocyanines. 2024. V.28. P.618-625. DOI: 10.1142/s1088424624500330 WOS Scopus OpenAlex
Dates:
Submitted: Apr 29, 2024
Accepted: Jun 7, 2024
Published online: Jul 9, 2024
Published print: Oct 31, 2024
Identifiers:
Web of science: WOS:001265779400001
Scopus: 2-s2.0-85198342345
OpenAlex: W4399737288
Citing: Пока нет цитирований
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