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Short- and long-range disorders in misfit layered compounds (MS)1.2+qNbS2 with the solid solution subsystem (MS) = (GdxDy1-xS) Научная публикация

Журнал Materials Research Bulletin
ISSN: 1873-4227 , E-ISSN: 0025-5408
Вых. Данные Год: 2020, Том: 131, Номер статьи : 110963, Страниц : 13 DOI: 10.1016/j.materresbull.2020.110963
Ключевые слова Rare-earth Sulfides, Misfit layered compounds, Real structure, Solid solutions
Авторы Sotnikov A.V. 1 , Bakovets V.V. 1 , Korotaev E.V. 1 , Trubina S.V. 1 , Zaikovskii V.I. 2
Организации
1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch of RAS, Akademika Lavrent’eva Avenue 3, Novosibirsk, 630090, Russian Federation
2 Boreskov Catalysis Institute, Siberian Branch of RAS, Akademika Lavrent’eva Avenue 5, Novosibirsk, 630090, Russian Federation

Реферат: We have synthesized misfit compounds (GdxDy1-xS)1.2+qNbS2 with a solid solution as a guest layer by sulfurization under CS2/H2S/Ar gas flow and consolidated them by pressure-assisted sintering. We have studied the real structure of polycrystalline samples at different scales (X-Ray diffraction, EXAFS, Raman spectroscopy, magnetic susceptibility and diffusion reflection spectroscopy). It has been shown that the microstructure of samples and the lattice structure disorders mainly determine the optical and magnetic properties of misfit compounds. The obtained data allowed us to describe correlations among changes in the real structures, phonon spectra, band-gap and exchange interactions of [GdxDy1-xS] and [NbS2] subsystems in misfit layered compounds.
Библиографическая ссылка: Sotnikov A.V. , Bakovets V.V. , Korotaev E.V. , Trubina S.V. , Zaikovskii V.I.
Short- and long-range disorders in misfit layered compounds (MS)1.2+qNbS2 with the solid solution subsystem (MS) = (GdxDy1-xS)
Materials Research Bulletin. 2020. V.131. 110963 :1-13. DOI: 10.1016/j.materresbull.2020.110963 WOS Scopus РИНЦ OpenAlex
Идентификаторы БД:
Web of science: WOS:000560378300006
Scopus: 2-s2.0-85086583350
РИНЦ: 43294554
OpenAlex: W3034645896
Цитирование в БД:
БД Цитирований
OpenAlex 9
Scopus 9
РИНЦ 12
Web of science 9
Альметрики: