Spin-crossover in iron(II) coordination compounds with 2,6-bis(benzimidazol-2-yl)pyridine

Spin-crossover in iron(II) coordination compounds with 2,6-bis(benzimidazol-2-yl)pyridine Full article

Journal

New Journal of Chemistry
ISSN: 1369-9261 , E-ISSN: 1144-0546

Output data

Year: 2020, Volume: 44, Number: 15, Pages: 5834-5840 Pages count : 7 DOI: 10.1039/d0nj00474j

Authors

Ivanova A.D. ¹ , Korotaev E.V. ¹ , Komarov V.Yu. ^1,2 , Sheludyakova L.A. ¹ , Varnek V.A. ¹ , Lavrenova L.G. ^1,2

Affiliations

1	Institute of Inorganic Chemistry Siberian Division of RAS, Novosibirsk, 630090, Russia
2	Novosibirsk National Research State University, Novosibirsk, 630090, Russia

New iron(II) complexes with 2,6-bis(benzimidazol-2-yl)pyridine (L), in particular, [FeL2]A2·nH2O (A = Br− (I), NO3− (II), C2N3− (III); n = 1 (I), 0.5 (II), 2 (III)) and [NiL2]Br2·1.23H2O·3.33EtOH (IV), have been synthesized and studied using single-crystal and powder X-ray diffraction techniques, UV-vis (diffuse reflection), IR and Mössbauer spectroscopy, as well as static magnetic susceptibility measurements. According to the experimental μeff(T) curves all the studied iron(II) compounds exhibit 1A1 ↔ 5T2 spin-crossover.

Ivanova A.D. , Korotaev E.V. , Komarov V.Y. , Sheludyakova L.A. , Varnek V.A. , Lavrenova L.G.
Spin-crossover in iron(II) coordination compounds with 2,6-bis(benzimidazol-2-yl)pyridine
New Journal of Chemistry. 2020. V.44. N15. P.5834-5840. DOI: 10.1039/d0nj00474j WOS Scopus РИНЦ OpenAlex

Web of science:	WOS:000531211600023
Scopus:	2-s2.0-85083638023
Elibrary:	43278246
OpenAlex:	W3011568086

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