Metal–organic frameworks based on polynuclear lanthanide complexes and octahedral rhenium clusters

Metal–organic frameworks based on polynuclear lanthanide complexes and octahedral rhenium clusters Full article

Journal

Inorganic chemistry frontiers
ISSN: 2052-1553 , E-ISSN: 2052-1545

Output data

Year: 2019, Volume: 6, Number: 6, Pages: 1518-1526 Pages count : 9 DOI: 10.1039/c9qi00339h

Authors

Litvinova Yulia M. ¹ , Gayfulin Yakov M. ¹ , van Leusen Jan ² , Samsonenko Denis G. ^1,3 , Lazarenko Vladimir A. ⁴ , Zubavichus Yan V. ⁵ , Kögerler Paul ² , Mironov Yuri V. ^1,3

Affiliations

1	Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentiev ave. 3, 630090 Novosibirsk, Russia
2	Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany
3	Novosibirsk State University, Pirogova str. 2, 630090 Novosibirsk, Russia
4	National Research Center "Kurchatov Institute", Kurchatov Square 1, 123182 Moscow, Russia
5	Federal Research Center Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia

The octahedral chalcocyanide cluster anion [Re6S8(CN)6]4– can serve as a metallolinker for the selfassembly of metal–organic frameworks (MOFs) comprising polynuclear lanthanide complexes, which have been illustrated for a series of nine compounds isolated as [{Ln4(μ3-OH)4(ina)4(H2O)n} {Re6S8(CN)6}]·mH2O (Ln = Pr – Er, ina = isonicotinate). Their solid-state framework structures are based on {Ln4(μ3-OH)4}8+ cubane fragments interlinked by isonicotinate and rhenium cyanide clusters. The coordination environment of the lanthanide ions, the coordination numbers and even the number of bridging isonicotinate moieties changes systematically within the lanthanide row, however, the framework topology remains unchanged, confirming the structure-directing role of the rhenium cluster. Structures, magnetochemical properties, luminescence and thermal stability of the new MOFs have been thoroughly analyzed.

Litvinova Y.M. , Gayfulin Y.M. , van Leusen J. , Samsonenko D.G. , Lazarenko V.A. , Zubavichus Y.V. , Kögerler P. , Mironov Y.V.
Metal–organic frameworks based on polynuclear lanthanide complexes and octahedral rhenium clusters
Inorganic chemistry frontiers. 2019. V.6. N6. P.1518-1526. DOI: 10.1039/c9qi00339h WOS Scopus РИНЦ OpenAlex

Web of science:	WOS:000472193200021
Scopus:	2-s2.0-85067249651
Elibrary:	41634880
OpenAlex:	W2944352503

DB	Citing
OpenAlex	33
Scopus	31
Elibrary	34